电子显微学报
電子顯微學報
전자현미학보
JOURNAL OF CHINESE ELECTRON MICROSCOPY SOCIETY
2015年
4期
281-285
,共5页
刘辉辉%贾双凤%盛华平%郑赫%王建波
劉輝輝%賈雙鳳%盛華平%鄭赫%王建波
류휘휘%가쌍봉%성화평%정혁%왕건파
氧化钴%钴孪晶%模板水热法%电子显微学
氧化鈷%鈷孿晶%模闆水熱法%電子顯微學
양화고%고련정%모판수열법%전자현미학
cobalt oxide%Co twinning%template hydrothermal method%transmission electron microscopy
通过模板水热法合成了氧化钴( CoO)纳米材料。用透射电子显微镜观察发现样品中CoO为岩盐立方结构,以纳米线的形态存在,每根纳米线均由尺寸在30~100 nm的纳米颗粒附着而成。同时,实验产物中也存在一些Co单质。 Co单质以纳米手指的形态存在,且多数具有孪晶结构,孪晶面为{111}。 Co孪晶的生成归因于高温高压的反应条件,同时Co单质的存在增强了CoO作为电极材料的导电性能。
通過模闆水熱法閤成瞭氧化鈷( CoO)納米材料。用透射電子顯微鏡觀察髮現樣品中CoO為巖鹽立方結構,以納米線的形態存在,每根納米線均由呎吋在30~100 nm的納米顆粒附著而成。同時,實驗產物中也存在一些Co單質。 Co單質以納米手指的形態存在,且多數具有孿晶結構,孿晶麵為{111}。 Co孿晶的生成歸因于高溫高壓的反應條件,同時Co單質的存在增彊瞭CoO作為電極材料的導電性能。
통과모판수열법합성료양화고( CoO)납미재료。용투사전자현미경관찰발현양품중CoO위암염립방결구,이납미선적형태존재,매근납미선균유척촌재30~100 nm적납미과립부착이성。동시,실험산물중야존재일사Co단질。 Co단질이납미수지적형태존재,차다수구유련정결구,련정면위{111}。 Co련정적생성귀인우고온고압적반응조건,동시Co단질적존재증강료CoO작위전겁재료적도전성능。
In this paper, Cobalt Oxide ( CoO) nanomaterial was synthesized by template hydrothermal method. Transmission electron microscopy observation proved that the CoO had rock?salt cubic structures which were in the form of nanoparticles?consisted nanowires. Meanwhile, the microstructure of the Co byproduct was also investigated in detail. Most of the Co were in nanofinger?shape, having the{111} twinning plane. The high temperature and high pressure were supposed to be responsible for the generation of the Co twinning. The conductivity of CoO electrode material was improved by the existence of Co.