广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2015年
15期
5-6,19
,共3页
螺噁嗪类化合物%环境响应型%光致变色%合成研究
螺噁嗪類化閤物%環境響應型%光緻變色%閤成研究
라오진류화합물%배경향응형%광치변색%합성연구
spirooxaine compounds%environmental response type%photochromic%preparation
螺噁嗪是一类重要的有机光致变色化合物,具有较高的化学稳定性、抗光疲劳性和光敏性,可根据环境中光谱的变化而发生变色反应,在建筑和汽车玻璃等多个领域具有广泛的应用。从螺噁嗪类化合物的基本合成思路出发,本文主要综述环境响应型单螺噁嗪类化合物、环境响应型双螺嗪类化合物及环境响应型螺噁嗪聚合物合成的方法,讨论了环境响应型螺噁嗪母环结构对于光致变色性质的影响,介绍了微波合成手段在环境响应型螺噁嗪类化合物合成中的应用,对其在合成方面重点研究的方向讨论并进行了展望。
螺噁嗪是一類重要的有機光緻變色化閤物,具有較高的化學穩定性、抗光疲勞性和光敏性,可根據環境中光譜的變化而髮生變色反應,在建築和汽車玻璃等多箇領域具有廣汎的應用。從螺噁嗪類化閤物的基本閤成思路齣髮,本文主要綜述環境響應型單螺噁嗪類化閤物、環境響應型雙螺嗪類化閤物及環境響應型螺噁嗪聚閤物閤成的方法,討論瞭環境響應型螺噁嗪母環結構對于光緻變色性質的影響,介紹瞭微波閤成手段在環境響應型螺噁嗪類化閤物閤成中的應用,對其在閤成方麵重點研究的方嚮討論併進行瞭展望。
라오진시일류중요적유궤광치변색화합물,구유교고적화학은정성、항광피로성화광민성,가근거배경중광보적변화이발생변색반응,재건축화기차파리등다개영역구유엄범적응용。종라오진류화합물적기본합성사로출발,본문주요종술배경향응형단라오진류화합물、배경향응형쌍라진류화합물급배경향응형라오진취합물합성적방법,토론료배경향응형라오진모배결구대우광치변색성질적영향,개소료미파합성수단재배경향응형라오진류화합물합성중적응용,대기재합성방면중점연구적방향토론병진행료전망。
As an important class of organic photochromic compounds, spirooxazine has a high chemical stability, photosensitivity and fatigue resistance to light, which can change color according to the changing environment in the spectral response, so it is also called environmental responses compounds in many areas, such as construction and automotive, spirooxazine compounds have wide application.In order to obtain better performance environment responsive spirooxazine compounds, they were designed and synthesized as a hot research.Staring with the review of the basic idea spirooxazine synthetic compounds, synthesis of spirooxazine of single compound, double spirooxazine spirooxazine compounds and polymers was studied, the environment-responsive spirooxazine parent ring structure of light-induced impact of color in nature was discussed, the application of microwave, ultrasound and other applications in the synthesis of compounds spirooxazine class were described and spirooxazine compounds in the synthesis of key research directions were discussed too.