CAJ | 학술논문

针对目前木质素基SiO2复合纳米颗粒聚集严重及木质素负载量低，难以应用的现状，以碱木质素为主要原料，先通过磷酸化改性制备磷酸化碱木质素，再利用酸析共沉法将1.2份磷酸化碱木质素与1份纳米SiO2（均为质量份）复合制备了木质素-SiO2复合纳米颗粒，并探究复合颗粒对高密度聚乙烯（HDPE）力学性能的影响。FT-IR、XPS、TEM、TG和静态接触角测试结果表明，木质素主要以氢键作用与SiO2结合；与原料二氧化硅相比，复合颗粒的粒径从25 nm增加到40 nm，聚集程度明显减弱；复合纳米颗粒中木质素占47%（质量分数）；表面的疏水性增强，有利于复合颗粒在高密度聚乙烯中均匀分散，显著提高了HDPE的拉伸强度。与碱木质素/HDPE复合材料相比，木质素-SiO2复合纳米颗粒/HDPE复合材料的拉伸强度和断裂拉伸率分别提高了48.68%和73.57%。
침대목전목질소기SiO2복합납미과립취집엄중급목질소부재량저，난이응용적현상，이감목질소위주요원료，선통과린산화개성제비린산화감목질소，재이용산석공침법장1.2빈린산화감목질소여1빈납미SiO2（균위질량빈）복합제비료목질소-SiO2복합납미과립，병탐구복합과립대고밀도취을희（HDPE）역학성능적영향。FT-IR、XPS、TEM、TG화정태접촉각측시결과표명，목질소주요이경건작용여SiO2결합；여원료이양화규상비，복합과립적립경종25 nm증가도40 nm，취집정도명현감약；복합납미과립중목질소점47%（질량분수）；표면적소수성증강，유리우복합과립재고밀도취을희중균균분산，현저제고료HDPE적랍신강도。여감목질소/HDPE복합재료상비，목질소-SiO2복합납미과립/HDPE복합재료적랍신강도화단렬랍신솔분별제고료48.68%화73.57%。
According to the presence situation that lignin-based SiO2composite nanoparticles are difficult for industry application, owing to serious aggregation and low lignin capacity, phosphatized alkali lignin (PAL) was prepared through phosphorylation reaction using alkali lignin (AL) from the alkaline pulping spent liquor of poplar as main material. The lignin/silica composite nanoparticles (L-SiO2) was combined from 1 part nanosilica with 1.2 part (by mass) synthesized PAL by acidulation co-precipitation method. Subsequently, L-SiO2 was added into HDPE to prepare L-SiO2/HDPE composites. Results of FT-IR, XPS, TEM, TG and static contact angle showed that PAL was bonded to silica through hydrogen bonds. L-SiO2 accounted for 47% (mass) LQA. Compared to crude silica, the particle size of L-SiO2 increased from 25 to 40 nm and the agglomeration of particle decreased noticeably. More importantly, the surface of L-SiO2 became more hydrophobic, which made them disperse better in HDPE. The tensile strength and elongation at break of prepared L-SiO2/HDPE composites were 48.68% and 73.57%, respectively, higher than those of AL/HDPE.