化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2015年
8期
3120-3129
,共10页
杨钊%程景才%杨超%梁斌
楊釗%程景纔%楊超%樑斌
양쇠%정경재%양초%량빈
膜%计算流体力学%渗透%多孔介质
膜%計算流體力學%滲透%多孔介質
막%계산류체역학%삼투%다공개질
membrane%computational fluid dynamics (CFD)%permeation%porous media
陶瓷膜因其化学稳定性好、机械强度大等优点得到广泛应用。计算流体力学(CFD)的快速发展使得计算模拟成为研究和优化陶瓷膜管结构性能的有效手段。为了优化非对称结构陶瓷膜管的结构和操作参数,对其渗透性能进行了CFD计算模拟。针对非对称结构陶瓷膜管的膜层和过渡层的厚度在10μm级的特点,采用Navier-Stokes方程和Darcy定律来分别描述膜管内和膜多孔介质内的纯水流动,利用多孔介质模型描述膜管的主体支撑层,用多孔跳跃边界简化膜管的膜层和过渡层,利用Konzey-Carmen方程对膜元件各层的渗透率进行估算。计算结果与实验值吻合较好,为优化陶瓷膜管的通道结构提供了便捷的工具。
陶瓷膜因其化學穩定性好、機械彊度大等優點得到廣汎應用。計算流體力學(CFD)的快速髮展使得計算模擬成為研究和優化陶瓷膜管結構性能的有效手段。為瞭優化非對稱結構陶瓷膜管的結構和操作參數,對其滲透性能進行瞭CFD計算模擬。針對非對稱結構陶瓷膜管的膜層和過渡層的厚度在10μm級的特點,採用Navier-Stokes方程和Darcy定律來分彆描述膜管內和膜多孔介質內的純水流動,利用多孔介質模型描述膜管的主體支撐層,用多孔跳躍邊界簡化膜管的膜層和過渡層,利用Konzey-Carmen方程對膜元件各層的滲透率進行估算。計算結果與實驗值吻閤較好,為優化陶瓷膜管的通道結構提供瞭便捷的工具。
도자막인기화학은정성호、궤계강도대등우점득도엄범응용。계산류체역학(CFD)적쾌속발전사득계산모의성위연구화우화도자막관결구성능적유효수단。위료우화비대칭결구도자막관적결구화조작삼수,대기삼투성능진행료CFD계산모의。침대비대칭결구도자막관적막층화과도층적후도재10μm급적특점,채용Navier-Stokes방정화Darcy정률래분별묘술막관내화막다공개질내적순수류동,이용다공개질모형묘술막관적주체지탱층,용다공도약변계간화막관적막층화과도층,이용Konzey-Carmen방정대막원건각층적삼투솔진행고산。계산결과여실험치문합교호,위우화도자막관적통도결구제공료편첩적공구。
Ceramic membranes have been widely used in chemical industry on account of their inherently superior physical integrity, chemical resistance and separation performance. Rapid development of computational fluid dynamics (CFD) has made numerical simulation an effective mean of researching and optimizing the structure and permeability of ceramic membrane tubes. In this paper the permeability of asymmetric ceramic membrane tubes was simulated with CFD in order to optimize the ceramic membrane tube structure and operating parameters. The thickness of ceramic top-layer and intermediate-layer of an asymmetrically-structured membrane is about tens of micron, so an effective simplified calculation model is put forward in this work. A porous media model was applied to the porous support of the ceramic membrane tube. The ceramic top-layer and intermediate-layer of the ceramic membrane tube were described with porous jump boundary conditions. The permeability of ceramic membrane was effectively evaluated by the classic Konzey-Carmen (KC) equation. The CFD results showed a good agreement with the experimental data. This quick and easy calculation method provides an effective tool to optimize the structure of membrane tubes.