广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2015年
15期
31-33,101
,共4页
爆震%抗爆剂%作用机理%高效环保
爆震%抗爆劑%作用機理%高效環保
폭진%항폭제%작용궤리%고효배보
knock%antiknock%the mechanism%efficient environmental protection
简述了国内外汽油抗爆剂的发展概况,对现有常规抗爆剂进行了评述。由于金属类抗爆剂存在对机车和环境的损伤问题,认为金属类抗爆剂将逐渐退出历史的舞台,高效环保型有机抗爆剂将是今后的发展方向。结合爆震原因、抗爆机理以及过氧化物反应规律,认为抗爆剂在起到抗爆作用时,各个基团是相互独立抗爆的,我们称之为基团贡献法,在此基础上总结出了高效环保型有机抗爆剂应该具有的基本性质,并认为基于芳基的异构类化合物将可能成为高效环保型抗爆剂的主要结构。
簡述瞭國內外汽油抗爆劑的髮展概況,對現有常規抗爆劑進行瞭評述。由于金屬類抗爆劑存在對機車和環境的損傷問題,認為金屬類抗爆劑將逐漸退齣歷史的舞檯,高效環保型有機抗爆劑將是今後的髮展方嚮。結閤爆震原因、抗爆機理以及過氧化物反應規律,認為抗爆劑在起到抗爆作用時,各箇基糰是相互獨立抗爆的,我們稱之為基糰貢獻法,在此基礎上總結齣瞭高效環保型有機抗爆劑應該具有的基本性質,併認為基于芳基的異構類化閤物將可能成為高效環保型抗爆劑的主要結構。
간술료국내외기유항폭제적발전개황,대현유상규항폭제진행료평술。유우금속류항폭제존재대궤차화배경적손상문제,인위금속류항폭제장축점퇴출역사적무태,고효배보형유궤항폭제장시금후적발전방향。결합폭진원인、항폭궤리이급과양화물반응규률,인위항폭제재기도항폭작용시,각개기단시상호독립항폭적,아문칭지위기단공헌법,재차기출상총결출료고효배보형유궤항폭제응해구유적기본성질,병인위기우방기적이구류화합물장가능성위고효배보형항폭제적주요결구。
The general situation of the development of gasoline antiknock both at home and abroad was briefly described, and the existing conventional antiknock agent were reviewed.Because of kind of antiknock damage by metal in cars and environment problems, metals antiknock would gradually withdrew from the historical stage, efficient and environmentally friendly organic antiknock agent would be the development direction in the future.Combining with the causes and mechanism of antiknock detonation, and peroxide reaction rule, it was realized that in the antiknock effect, each group was independent of anti-explosion, which was the group contribution, it was summarized that the efficient and environmentally friendly organic antiknock should had the basic nature, and multiple heterogeneous aromatic hydrocarbon based on aromatic compounds could be efficient and environmentally friendly antiknock main structure.