广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2015年
14期
48-50
,共3页
茶籽壳活性炭%制备条件%化学表面处理%重金属及贵金属%吸附
茶籽殼活性炭%製備條件%化學錶麵處理%重金屬及貴金屬%吸附
다자각활성탄%제비조건%화학표면처리%중금속급귀금속%흡부
activated carbon of tea seed shell%preparation conditions%chemical surface treatment%heavy metals and precious metals%adsorption
研究了茶籽壳活性炭的制备条件及化学表面处理的方法与效果。活性炭制备条件包括二种不同活化剂的浓度、高温炭化时间和高温炭化温度。实验结果表明:选用60%的ZnCl2溶液为活化剂,低、高温炭化时间为3+3 h,低、高温炭化温度为300+600℃时,所制备的茶籽壳活性炭的比表面积为:1023.5 g/m2。用硝酸及氨水对所制得的活性炭进行表面处理,能有效提高其活性炭对重金属和贵金属的吸附能力。实验结果表明:用氨水处理的活性炭,对重金属铅的吸附量提高了约41%,对贵金属银的吸附量提高约27%;用硝酸处理的活性炭,对重金属铅的吸附量提高了约53%,对贵金属银的吸附量提高约41%。可用于重金属废水的处理及贵金属的吸附回收。
研究瞭茶籽殼活性炭的製備條件及化學錶麵處理的方法與效果。活性炭製備條件包括二種不同活化劑的濃度、高溫炭化時間和高溫炭化溫度。實驗結果錶明:選用60%的ZnCl2溶液為活化劑,低、高溫炭化時間為3+3 h,低、高溫炭化溫度為300+600℃時,所製備的茶籽殼活性炭的比錶麵積為:1023.5 g/m2。用硝痠及氨水對所製得的活性炭進行錶麵處理,能有效提高其活性炭對重金屬和貴金屬的吸附能力。實驗結果錶明:用氨水處理的活性炭,對重金屬鉛的吸附量提高瞭約41%,對貴金屬銀的吸附量提高約27%;用硝痠處理的活性炭,對重金屬鉛的吸附量提高瞭約53%,對貴金屬銀的吸附量提高約41%。可用于重金屬廢水的處理及貴金屬的吸附迴收。
연구료다자각활성탄적제비조건급화학표면처리적방법여효과。활성탄제비조건포괄이충불동활화제적농도、고온탄화시간화고온탄화온도。실험결과표명:선용60%적ZnCl2용액위활화제,저、고온탄화시간위3+3 h,저、고온탄화온도위300+600℃시,소제비적다자각활성탄적비표면적위:1023.5 g/m2。용초산급안수대소제득적활성탄진행표면처리,능유효제고기활성탄대중금속화귀금속적흡부능력。실험결과표명:용안수처리적활성탄,대중금속연적흡부량제고료약41%,대귀금속은적흡부량제고약27%;용초산처리적활성탄,대중금속연적흡부량제고료약53%,대귀금속은적흡부량제고약41%。가용우중금속폐수적처리급귀금속적흡부회수。
Preparation conditions and surface treatment effect of the activated carbon for tea seed shell was studied. Parameters such as concentration of the activator, carbonization temperature and carbonization time were also studied.The result showed that the activator was 60% ZnCl2 solution, low and high temperature carbonization time were 3+3 h, low and high temperature carbonization temperature were 300+600 ℃, surface area of the activated carbon of tea seed shell was 1023.5 g/m2 .Adsorption ability for heavy metals and precious metals could be effectively improved that activated carbon was surface-treated with nitric acid and ammonia.The results showed that activated carbon treated with ammonia for the adsorption amount of Pb increased about 41%and the adsorption amount of Ag increased about 27%.Activated carbon treated with nitric acid for the adsorption amount of Pb increased about 53% and the adsorption amount of Ag increased about 41%.It could be used for treatment of heavy metal wastewater and adsorption recovery of precious metals.