东北大学学报(自然科学版)
東北大學學報(自然科學版)
동북대학학보(자연과학판)
JOURNAL OF NORTHEASTERN UNIVERSITY(NATURAL SCIENCE)
2015年
8期
1184-1187,1198
,共5页
冯雅丽%易爱飞%李浩然%王维大
馮雅麗%易愛飛%李浩然%王維大
풍아려%역애비%리호연%왕유대
玉米秸秆%高铁低品位锰矿%硫酸预处理%还原性有机物%黄钾铁钒
玉米秸稈%高鐵低品位錳礦%硫痠預處理%還原性有機物%黃鉀鐵釩
옥미갈간%고철저품위맹광%류산예처리%환원성유궤물%황갑철범
cornstalk%low-grade manganese ore with high-content iron%pre-processing with sulfuric acid%reductive organics%jarosite
采用“玉米秸秆硫酸预处理—浸出”工艺处理含Mn 9.63%(质量分数)的朝阳锰矿.通过试验考察用硫酸对玉米秸秆进行预处理的时间、秸秆用量、温度、硫酸浓度和浸出温度对锰浸出率的影响.试验表明,在秸秆用量2.5 g、时间10 min、硫酸浓度1.2 mol/L、温度80℃时预处理秸秆,浸出温度为90℃的条件下,锰的浸出率达92%,杂质铁溶出率仅为20%.玉米秸秆处理前后FTIR分析结果表明,对秸秆进行硫酸预处理能够破坏难降解的木质素结构,有利于提高锰的浸出效果.
採用“玉米秸稈硫痠預處理—浸齣”工藝處理含Mn 9.63%(質量分數)的朝暘錳礦.通過試驗攷察用硫痠對玉米秸稈進行預處理的時間、秸稈用量、溫度、硫痠濃度和浸齣溫度對錳浸齣率的影響.試驗錶明,在秸稈用量2.5 g、時間10 min、硫痠濃度1.2 mol/L、溫度80℃時預處理秸稈,浸齣溫度為90℃的條件下,錳的浸齣率達92%,雜質鐵溶齣率僅為20%.玉米秸稈處理前後FTIR分析結果錶明,對秸稈進行硫痠預處理能夠破壞難降解的木質素結構,有利于提高錳的浸齣效果.
채용“옥미갈간류산예처리—침출”공예처리함Mn 9.63%(질량분수)적조양맹광.통과시험고찰용류산대옥미갈간진행예처리적시간、갈간용량、온도、류산농도화침출온도대맹침출솔적영향.시험표명,재갈간용량2.5 g、시간10 min、류산농도1.2 mol/L、온도80℃시예처리갈간,침출온도위90℃적조건하,맹적침출솔체92%,잡질철용출솔부위20%.옥미갈간처리전후FTIR분석결과표명,대갈간진행류산예처리능구파배난강해적목질소결구,유리우제고맹적침출효과.
Utilizing cornstalk pre-processing with sulfuric acid,leaching experiments were carried out to dispose of manganese ore containing Mn of 9. 63%.The effects of pre-process time, cornstalk dosage,pre-process temperature,concentration of sulfuric acid and leaching temperature on manganese dissolution were investigated.The results showed that in the condition of pre-process cornstalk with dilute acid at 80oC,2. 5 g of cornstalk and concentration of H2SO4 1. 2 mol/L for 10 minutes,leaching manganese using pre-processed cornstalk as a reductant for 90 minutes at 90℃could dissolve 92%of the manganese,and less than 20%Fe was dissolved.The FTIR analysis results indicated that cornstalk pre-processed with acid could destroy the structure of lignin,which is beneficial to leaching.