CAJ | 학술논문

以实验室合成的七苯基?单氯丙基 POSS（POSS?Cl）为原子转移自由基聚合（ATRP）的引发剂，合成了含 POSS 的聚甲基丙烯酸三氟乙酯（PTFEMA）均聚物（POSS?PTFEMA）、POSS 聚甲基丙烯酸甲酯?b?聚甲基丙烯酸三氟乙酯（POSS?PMMA?b?PTFEMA）和 POSS 聚甲基丙烯酸三氟乙酯?b?聚甲基丙烯酸甲酯（POSS?PTFEMA?b?PMMA）的 POSS 嵌段共聚物。利用傅里叶红外光谱（FT?IR）、核磁共振（NMR）等方法确定了 POSS 聚合物的结构，凝胶渗透色谱（GPC）表征了 POSS 聚合物的分子量和分子量分布。热失重（TGA）分析表明，3种 POSS 聚合物表现出良好的热稳定性能。对聚合物膜的疏水疏油性研究表明，聚合物膜对水接触角为97°～101°，对正十二烷的接触角则为36°～40°，且随聚合物中TFEMA 聚合度的增大，表面能减小，接触角随之增大。
이실험실합성적칠분기?단록병기 POSS（POSS?Cl）위원자전이자유기취합（ATRP）적인발제，합성료함 POSS 적취갑기병희산삼불을지（PTFEMA）균취물（POSS?PTFEMA）、POSS 취갑기병희산갑지?b?취갑기병희산삼불을지（POSS?PMMA?b?PTFEMA）화 POSS 취갑기병희산삼불을지?b?취갑기병희산갑지（POSS?PTFEMA?b?PMMA）적 POSS 감단공취물。이용부리협홍외광보（FT?IR）、핵자공진（NMR）등방법학정료 POSS 취합물적결구，응효삼투색보（GPC）표정료 POSS 취합물적분자량화분자량분포。열실중（TGA）분석표명，3충 POSS 취합물표현출량호적열은정성능。대취합물막적소수소유성연구표명，취합물막대수접촉각위97°～101°，대정십이완적접촉각칙위36°～40°，차수취합물중TFEMA 취합도적증대，표면능감소，접촉각수지증대。
Three tadpole?shaped POSS fluorinated acrylate polymers, POSS?poly (trifluoroethyl acrylate) (POSS?PTFEMA), POSS?poly ( methyl methacrylate)?b?poly ( trifluoroethyl methacrylate) ( POSS?PMMA?b?PTFEMA) and POSS?poly ( trifluoroethyl methacrylate)?b?poly ( methyl methacrylate) ( POSS?PTFEMA?b?PMMA), were synthesized via atom transfer radical polymerization (ATRP) using 3?chloropropyl?hepta (phenyl) POSS (POSS?Cl) as the initiator. The structures of the initiator and the related three hybrid polymers were characterized with fou?rier transform infrared (FT?IR) spectroscopy and nuclear magnetic resonance (NMR) techniques, and the molecu?lar weights and molecular weight distributions were determined with gel permeation chromatography ( GPC). Thermal stabilities of the hybrid polymers were evaluated by thermal gravimetric (TG) method, and the results in?dicated that the hybrid polymers exhibited excellent thermal stability. In addition, surface hydrophobic and oleopho?bic properties of the hybrid polymers were shown that on the polymer films the water contact angles were about 97°~101°, and the dihexyl contact angles were about 36° ~40°. Furthermore, it was found that with the increasing of the degree of polymerization of TFEMA, the surface energy was decreased which leaded higher contact angles.