中国涂料
中國塗料
중국도료
CHINA PAINT
2015年
7期
37-41
,共5页
聚乙烯醇%硅酸钠%顺丁烯二酸酐%杂化反应%耐水性
聚乙烯醇%硅痠鈉%順丁烯二痠酐%雜化反應%耐水性
취을희순%규산납%순정희이산항%잡화반응%내수성
polyvinyl-alcohol%sodium silicate%maleic anhydride%hybridization reaction%water resistance
以马来酸酐(MAH)对聚乙烯醇(PVA)接枝，然后在硫酸的催化作用下与硅酸钠反应，制备有机-无机复合材料。利用FTIR、DSC、TGA对所制备的材料进行表征，研究了MAH接枝PVA(PVA-MAH)的接枝率、硅酸钠含量以及成型条件对复合材料性能的影响。研究结果表明，马来酸酐接枝PVA与SiO2之间能够形成有机无机杂化结构，当PVA-MAH接枝率和硅酸钠含量适当时，复合材料具有较好的耐水性及热稳定性。
以馬來痠酐(MAH)對聚乙烯醇(PVA)接枝，然後在硫痠的催化作用下與硅痠鈉反應，製備有機-無機複閤材料。利用FTIR、DSC、TGA對所製備的材料進行錶徵，研究瞭MAH接枝PVA(PVA-MAH)的接枝率、硅痠鈉含量以及成型條件對複閤材料性能的影響。研究結果錶明，馬來痠酐接枝PVA與SiO2之間能夠形成有機無機雜化結構，噹PVA-MAH接枝率和硅痠鈉含量適噹時，複閤材料具有較好的耐水性及熱穩定性。
이마래산항(MAH)대취을희순(PVA)접지，연후재류산적최화작용하여규산납반응，제비유궤-무궤복합재료。이용FTIR、DSC、TGA대소제비적재료진행표정，연구료MAH접지PVA(PVA-MAH)적접지솔、규산납함량이급성형조건대복합재료성능적영향。연구결과표명，마래산항접지PVA여SiO2지간능구형성유궤무궤잡화결구，당PVA-MAH접지솔화규산납함량괄당시，복합재료구유교호적내수성급열은정성。
Polyvinyl alcohol (PVA) was grafted by Maleic anhydride (MAH) and then reacted with sodium silicate under the catalysis of sulfuric acid to prepare organic-inorganic composite materials. FTIR, DSC and TGA were used to characterize the material prepared as above, to research the effect of PVA-MAH graft ratio, sodium silicate content and molding conditions on the properties of the composites. The results showed that the organic - inorganic hybrid structure could be formed between MAH-grafted PVA and SiO2 and the composite materials had preferable water and thermal stabilities when the PVA-MAH graft ratio and sodium silicate content were suitable.
