CAJ | 학술논문

膦(磷)酸功能化硅氧烷质子交换膜是最有望应用于高温质子交换膜的新材料。综述了膦(磷)酸功能化硅氧烷高温质子交换膜的研究进展，重点讨论了环氧开环、自由基共聚、形成酸碱对以及膦酸酯基硅氧烷水解交联4种不同的将膦(磷)酸键合在杂化膜中的方式，并从物理化学稳定性、电导率等方面比较各种质子交换膜的性能，最后展望了膦(磷)酸功能化硅氧烷高温质子交换膜的发展趋势。
련(린)산공능화규양완질자교환막시최유망응용우고온질자교환막적신재료。종술료련(린)산공능화규양완고온질자교환막적연구진전，중점토론료배양개배、자유기공취、형성산감대이급련산지기규양완수해교련4충불동적장련(린)산건합재잡화막중적방식，병종물이화학은정성、전도솔등방면비교각충질자교환막적성능，최후전망료련(린)산공능화규양완고온질자교환막적발전추세。
Phosphonic (phosphoric)acid functionalized siloxane proton exchange membrane is one of the most promising new materials applied in high-temperature proton exchange membrane.The research progress about phos-phonic (phosphoric)acid functionalized silicone used as high-temperature proton exchange membranes is reviewed, with emphasis on chemically bond phosphonic acid onto hybrid membranes,including epoxy ring opening,free radical copolymerization,acid-base reaction and hydrolysis crosslinking of phosphate functionalized silicas.In addition,vari-ous kinds of proton exchange membranes properties are compared in terms of physical and chemical stability,and elec-trical conductivity,and finally a perspective upon their future development trend is presented.