CAJ | 학술논문

为开发新型卷烟保润剂，以D-果糖和糠醛为起始原料，设计合成了一种新化合物1-O-[3-(2-呋喃基)丙烯酰基]-β-D-吡喃果糖（VIII），用IR，1H NMR，13C NMR，ESI-MS和元素分析表征了VIII的结构，并进行了添加于烟丝后的物理保润性能测试、热裂解分析、卷烟烟气安全性生物学评价和感官质量评价。结果显示：①所合成的化合物为目标产物；②VIII在干燥条件下的物理保润性能优于丙二醇；③VIII热裂解时会释放出呋喃类香味成分；④添加VIII的试验卷烟和空白卷烟的烟气生物学效应相当；⑤VIII可降低卷烟烟气干燥感和刺激性，提高烟气香气量及改善余味。
위개발신형권연보윤제，이D-과당화강철위기시원료，설계합성료일충신화합물1-O-[3-(2-부남기)병희선기]-β-D-필남과당（VIII），용IR，1H NMR，13C NMR，ESI-MS화원소분석표정료VIII적결구，병진행료첨가우연사후적물리보윤성능측시、열렬해분석、권연연기안전성생물학평개화감관질량평개。결과현시：①소합성적화합물위목표산물；②VIII재간조조건하적물리보윤성능우우병이순；③VIII열렬해시회석방출부남류향미성분；④첨가VIII적시험권연화공백권연적연기생물학효응상당；⑤VIII가강저권연연기간조감화자격성，제고연기향기량급개선여미。
In order to develop novel cigarette humectants, a new compound, Ⅷ, was designed and synthesized with D-fructose and furfural as starting materials. The structure of the product was characterized by IR, 1H NMR, 13C NMR, ESI-MS and elemental analysis. The moisture retentivity test, pyrolysis analysis, biological effects assessment of tobacco smoke were conducted after the product being applied to cigarette, and the sensory quality of cigarette was also evaluated. The results showed that: 1) The obtained product was proved to be the target compound 1-O-[3-(2-furanyl)acryloyl]-β-D-fructopyranose. 2) The moisture retentivity of Ⅷ was better than that of propylene glycol in dry environments. 3) Ⅷreleased aromatic furan constituents during pyrolysis. 4) The cigarettes added with Ⅷ were comparable to blank cigarettes in the biological effects of smoke. 5) Ⅷ reduced the dryness and irritation, increased the aroma, and improved the aftertaste of cigarette smoke.