化学研究
化學研究
화학연구
CHEMICAL RESEARCHES
2015年
5期
519-523
,共5页
王擎龙%李海燕%刘金凤%李秋叶%杨建军
王擎龍%李海燕%劉金鳳%李鞦葉%楊建軍
왕경룡%리해연%류금봉%리추협%양건군
Ag3 VO4%水热法%可见光催化%甲基橙%罗丹明B
Ag3 VO4%水熱法%可見光催化%甲基橙%囉丹明B
Ag3 VO4%수열법%가견광최화%갑기등%라단명B
Ag3 VO4%hydrothermal method%visible-light-driven photocatalysis%methyl or-ange%rhodamine B
以V2 O5、NaO H和AgNO3为原料,采用水热法制备了可见光催化剂Ag3 VO4.考察了水热温度对该催化剂可见光吸收以及可见光催化性能的影响.以有机染料甲基橙(M O )和罗丹明B (RhB )为指标反应,测试了Ag3 VO4的可见光催化活性.结果表明,不同水热温度下的催化剂均在可见光区有明显的吸收,吸收带边约为590~650 nm ;在160℃水热反应4 h制得的Ag3 VO4光催化活性最高,当Ag3 VO4用量为01. g时,对于10 mg/L甲基橙溶液3 h的脱色率可达到94%,对10 m g/L罗丹明B 1 h的脱色率则可达到98%.
以V2 O5、NaO H和AgNO3為原料,採用水熱法製備瞭可見光催化劑Ag3 VO4.攷察瞭水熱溫度對該催化劑可見光吸收以及可見光催化性能的影響.以有機染料甲基橙(M O )和囉丹明B (RhB )為指標反應,測試瞭Ag3 VO4的可見光催化活性.結果錶明,不同水熱溫度下的催化劑均在可見光區有明顯的吸收,吸收帶邊約為590~650 nm ;在160℃水熱反應4 h製得的Ag3 VO4光催化活性最高,噹Ag3 VO4用量為01. g時,對于10 mg/L甲基橙溶液3 h的脫色率可達到94%,對10 m g/L囉丹明B 1 h的脫色率則可達到98%.
이V2 O5、NaO H화AgNO3위원료,채용수열법제비료가견광최화제Ag3 VO4.고찰료수열온도대해최화제가견광흡수이급가견광최화성능적영향.이유궤염료갑기등(M O )화라단명B (RhB )위지표반응,측시료Ag3 VO4적가견광최화활성.결과표명,불동수열온도하적최화제균재가견광구유명현적흡수,흡수대변약위590~650 nm ;재160℃수열반응4 h제득적Ag3 VO4광최화활성최고,당Ag3 VO4용량위01. g시,대우10 mg/L갑기등용액3 h적탈색솔가체도94%,대10 m g/L라단명B 1 h적탈색솔칙가체도98%.
Ag3 VO4 ,a visible‐light‐driven photocatalyst ,was prepared by hydrothermal method with V2 O5 、NaOH and AgNO3 acted as materials .The effect of hydrothermal temperature on the visible light absorption and photocatalytic activity of Ag3 VO4 were systematically investiga‐ted .The visible light photocatalytic activity of Ag3 VO4 was evaluated by using organic dye methyl orange (MO) and rhodamine B (RhB) as evaluation system ,respectively .The results indicated that the obtained Ag3 VO4 photocatalyst at different hydrothermal temperature showed obvious absorbance in the visible light region and the absorption band edge centered at ca 590-650 nm .Moreover ,Ag3 VO4 obtained at 160 ℃ for 4 h exhibited the highest visible‐light‐driven activity .As Ag3 VO4 dosage being 0 .1 g ,the degradation yield of methyl orange with the concentration of 10 mg/L reached 94% after 3 h and while that of rhodamine B with the same concentration reached 98% after 1 h .