工业安全与环保
工業安全與環保
공업안전여배보
INDUSTRIAL SAFETY AND ENVIRONMENTAL PROTECTION
2015年
8期
83-85
,共3页
涂保华%储云%钱伟%张鸿涛%陈兆林%董良飞
塗保華%儲雲%錢偉%張鴻濤%陳兆林%董良飛
도보화%저운%전위%장홍도%진조림%동량비
循环冷却水%缓蚀阻垢剂%低磷
循環冷卻水%緩蝕阻垢劑%低燐
순배냉각수%완식조구제%저린
circulating cooling water%corrosion inhibitor%low phosphorus
在实验室合成绿色无磷阻垢剂聚环氧琥珀酸(PESA ),进行结构表征与性能测试,表明合成产物有较好的阻垢性能。将聚环氧琥珀酸与氨基三亚甲基膦酸(ATMP)、羟基亚乙基二膦酸(HEDP)进行复配的试验表明,在投加质量浓度分别为25,15,10 mg/L时,能达到理想的缓蚀阻垢效果。对复配药剂阻垢机理的探讨表明,药剂分子的螯合和分散作用改变了碳酸钙的晶型,一定程度上阻止了垢的沉积。
在實驗室閤成綠色無燐阻垢劑聚環氧琥珀痠(PESA ),進行結構錶徵與性能測試,錶明閤成產物有較好的阻垢性能。將聚環氧琥珀痠與氨基三亞甲基膦痠(ATMP)、羥基亞乙基二膦痠(HEDP)進行複配的試驗錶明,在投加質量濃度分彆為25,15,10 mg/L時,能達到理想的緩蝕阻垢效果。對複配藥劑阻垢機理的探討錶明,藥劑分子的螯閤和分散作用改變瞭碳痠鈣的晶型,一定程度上阻止瞭垢的沉積。
재실험실합성록색무린조구제취배양호박산(PESA ),진행결구표정여성능측시,표명합성산물유교호적조구성능。장취배양호박산여안기삼아갑기련산(ATMP)、간기아을기이련산(HEDP)진행복배적시험표명,재투가질량농도분별위25,15,10 mg/L시,능체도이상적완식조구효과。대복배약제조구궤리적탐토표명,약제분자적오합화분산작용개변료탄산개적정형,일정정도상조지료구적침적。
Green scale inhibitor polyepoxysuccinic acid (PESA ) has been synthesized in the laboratory .Structural charac-terization and performance tests show that synthetic products have good scale performance .The tests of the complex of PE-SA ,amino trimethylene phosphonic acid (ATMP) and hydroxy-ethylidene diphosphonic acid (HEDP) show that when the concentration of the dosing is 25 ,15 ,10 mg/L respectively ,the complex can achieve the desired effect .The investigation of the mechanism of inhibition of the complex shows that chelating agents and dispersing agents of the molecule have changed the role of calcium carbonate polymorphs ,which prevents the deposition of fouling to some extent .