云南化工
雲南化工
운남화공
YUNNAN CHEMICAL TECHNOLOGY
2015年
4期
36-38
,共3页
叔胺%氟化铵%氟化氢
叔胺%氟化銨%氟化氫
숙알%불화안%불화경
tertiary amine%ammonium fluoride%hydrogen fluoride
探索了叔胺分解氟化铵制氨气和氟化氢的方法。以叔胺作为萃取剂,在极性溶剂、水的存在下分解氟化铵释放出氨气;然后,加入高沸点的非极性溶剂蒸发出水和极性溶剂;最后,在更高的温度下,实现叔胺氟化盐的分解,释放出氟化氢;最终,达到将氟化铵分解,并分步释放出氨气和氟化氢。
探索瞭叔胺分解氟化銨製氨氣和氟化氫的方法。以叔胺作為萃取劑,在極性溶劑、水的存在下分解氟化銨釋放齣氨氣;然後,加入高沸點的非極性溶劑蒸髮齣水和極性溶劑;最後,在更高的溫度下,實現叔胺氟化鹽的分解,釋放齣氟化氫;最終,達到將氟化銨分解,併分步釋放齣氨氣和氟化氫。
탐색료숙알분해불화안제안기화불화경적방법。이숙알작위췌취제,재겁성용제、수적존재하분해불화안석방출안기;연후,가입고비점적비겁성용제증발출수화겁성용제;최후,재경고적온도하,실현숙알불화염적분해,석방출불화경;최종,체도장불화안분해,병분보석방출안기화불화경。
This paper studied the decomposition of ammonium fluoride for production of ammonia and hydrogen fluoride.Tertiary amine as extraction agent,in the presence of water,ammonium fluoride released ammonia in a polar solvent;then adding non -polar solvents with high -boiling point,polar solvents and wa-ter was distilled;finally,at higher temperature,the decomposition of tertiary amine fluoride was achieved,hy-drogen fluoride was released;eventually,the decomposition of ammonium fluoride was reached,and the am-monia and hydrogen fluoride were stepwise released.