装备环境工程
裝備環境工程
장비배경공정
EQUIPMENT ENVIRONMENTAL ENGINEERING
2015年
4期
129-136,141
,共9页
王新印%周亚茹%张鉴清%曹发和
王新印%週亞茹%張鑒清%曹髮和
왕신인%주아여%장감청%조발화
镁合金%腐蚀%析氢%负差数效应%扫描电化学显微镜
鎂閤金%腐蝕%析氫%負差數效應%掃描電化學顯微鏡
미합금%부식%석경%부차수효응%소묘전화학현미경
magnesium alloy%corrosion%hydrogen evolution%negative difference effect%SECM
综述目前镁及其合金腐蚀过程中析氢的研究现状,阐述镁合金腐蚀过程中的析氢特点,并对已有解释镁合金析氢负差数效应的理论及存在的问题进行了总结,同时还概括了氢气对镁合金腐蚀的影响,回顾了传统测量氢气的方法及存在的问题,重点介绍了扫描电化学显微镜微区定量收集氢气的新方法,以及应用扫描电化学显微镜研究纯镁腐蚀过程中微区析氢行为。
綜述目前鎂及其閤金腐蝕過程中析氫的研究現狀,闡述鎂閤金腐蝕過程中的析氫特點,併對已有解釋鎂閤金析氫負差數效應的理論及存在的問題進行瞭總結,同時還概括瞭氫氣對鎂閤金腐蝕的影響,迴顧瞭傳統測量氫氣的方法及存在的問題,重點介紹瞭掃描電化學顯微鏡微區定量收集氫氣的新方法,以及應用掃描電化學顯微鏡研究純鎂腐蝕過程中微區析氫行為。
종술목전미급기합금부식과정중석경적연구현상,천술미합금부식과정중적석경특점,병대이유해석미합금석경부차수효응적이론급존재적문제진행료총결,동시환개괄료경기대미합금부식적영향,회고료전통측량경기적방법급존재적문제,중점개소료소묘전화학현미경미구정량수집경기적신방법,이급응용소묘전화학현미경연구순미부식과정중미구석경행위。
The research status of hydrogen evolution during magnesium alloy′s corrosion process and the feature of hydrogen evolution were reviewed. In addition, we also summarized those theories for Negative Difference Effect (NDE) during magnesium corrosion and discussed the corresponding shortcomings. The effects of hydrogen on magnesium′s corrosion behavior were generalized. Moreover, the classical method to measure the hydrogen evolution were reviewed and its disadvantages were pointed out. Finally, the Scanning Electrochemical Microscopy (SECM) was introduced as a new method to detect the hydrogen, as well as our work on hydrogen evolution and spatial distribution based on SECM.