导弹与航天运载技术
導彈與航天運載技術
도탄여항천운재기술
MISSILES AND SPACE VEHICLES
2015年
4期
100-102
,共3页
钟秋%徐光%李俊%米思巍
鐘鞦%徐光%李俊%米思巍
종추%서광%리준%미사외
毛细管-气相色谱法%高纯级无水肼%挥发性含碳化合物
毛細管-氣相色譜法%高純級無水肼%揮髮性含碳化閤物
모세관-기상색보법%고순급무수정%휘발성함탄화합물
Capillary column-gas chromatography%Anhydrous hydrazine of high purity grade%Volatile carbonaceous material
建立一种高纯级无水肼样品中挥发性含碳化合物的毛细管-气相色谱分析方法,并针对实际样品进行定性和定量测定。结果表明,偏二甲肼、乙醇和甲基肼的加标回收率均在91.6%~107.7%范围内,挥发性含碳化合物总平均回收率达到101.1%;3种物质的相对标准偏差(RSD)均在1.7%~4.1%范围内,挥发性含碳化合物的相对标准偏差为3.0%。
建立一種高純級無水肼樣品中揮髮性含碳化閤物的毛細管-氣相色譜分析方法,併針對實際樣品進行定性和定量測定。結果錶明,偏二甲肼、乙醇和甲基肼的加標迴收率均在91.6%~107.7%範圍內,揮髮性含碳化閤物總平均迴收率達到101.1%;3種物質的相對標準偏差(RSD)均在1.7%~4.1%範圍內,揮髮性含碳化閤物的相對標準偏差為3.0%。
건립일충고순급무수정양품중휘발성함탄화합물적모세관-기상색보분석방법,병침대실제양품진행정성화정량측정。결과표명,편이갑정、을순화갑기정적가표회수솔균재91.6%~107.7%범위내,휘발성함탄화합물총평균회수솔체도101.1%;3충물질적상대표준편차(RSD)균재1.7%~4.1%범위내,휘발성함탄화합물적상대표준편차위3.0%。
A method for determination of volatile carbonaceous material in anhydrous hydrazine of high purity grade by capillary column-gas chromatography was developed, which was also applied to the qualitative and quantitative analysis of real samples. The results showed that the spiked recoveries of unsymmetrical dimethylhydrazine, ethanol and monomethyl hydrazine were all between 91.6%and 107.7%, the average recovery of volatile carbonaceous material was 101.1%;and relative standard deviations (RSDs) of three components were between 1.7%and 4.1%, the RSD of volatile carbonaceous material was 3.0%.