天然气化工（C1化学与化工）
天然氣化工（C1化學與化工）
천연기화공（C1화학여화공）
Natural Gas Chemical Industry
2015年
4期
74-78,102
,共6页
醋酸乙烯%醋酸锌%活性炭%乙炔%醋酸%催化剂
醋痠乙烯%醋痠鋅%活性炭%乙炔%醋痠%催化劑
작산을희%작산자%활성탄%을결%작산%최화제
vinyl acetate%zinc acetate%activated carbon%acetylene%acetic acid%catalyst
国内主要采用乙炔气相法工艺合成醋酸乙烯。该工艺以醋酸锌/活性炭催化剂，其经过近一个世纪的发展性能有了较大提高，但仍存在活性低、寿命短等方面的不足。本文从反应及失活机理、活性组分、载体、助催化剂及催化剂制备工艺等5个方面总结了乙炔气相法合成醋酸乙烯催化剂方面的研究进展。
國內主要採用乙炔氣相法工藝閤成醋痠乙烯。該工藝以醋痠鋅/活性炭催化劑，其經過近一箇世紀的髮展性能有瞭較大提高，但仍存在活性低、壽命短等方麵的不足。本文從反應及失活機理、活性組分、載體、助催化劑及催化劑製備工藝等5箇方麵總結瞭乙炔氣相法閤成醋痠乙烯催化劑方麵的研究進展。
국내주요채용을결기상법공예합성작산을희。해공예이작산자/활성탄최화제，기경과근일개세기적발전성능유료교대제고，단잉존재활성저、수명단등방면적불족。본문종반응급실활궤리、활성조분、재체、조최화제급최화제제비공예등5개방면총결료을결기상법합성작산을희최화제방면적연구진전。
In China, vinyl acetate (VAc) was produced mainly by gas phase synthesis from acetylene and acetic acid. The carbon-supported zinc acetate was used as the catalyst for this process, which had been greatly improved in past near a century, however, the disadvantages of low activity and short life were still in existence. Advances in research on the catalysts were reviewed, including the reaction and deactivation mechanisms, active components, supports, promoters and catalyst preparation.
