火炸药学报
火炸藥學報
화작약학보
CHINESE JOURNAL OF EXPLOSIVES & PROPELLANTS
2015年
4期
22-26
,共5页
王晶禹%高康%徐文峥%叶宝云%徐洋
王晶禹%高康%徐文崢%葉寶雲%徐洋
왕정우%고강%서문쟁%협보운%서양
物理化学%复合粒子%CL-2 0%硬脂酸钙%撞击感度%热稳定性%水悬浮法
物理化學%複閤粒子%CL-2 0%硬脂痠鈣%撞擊感度%熱穩定性%水懸浮法
물이화학%복합입자%CL-2 0%경지산개%당격감도%열은정성%수현부법
physical chemistry%composite particle%CL-20%CaSt2%impact sensitivity%thermal stability%water slurry method
以CL-20为主体炸药、Estane5703为黏结剂、硬脂酸钙(CaSt2)为增塑剂,采用水悬浮法制备了4种复合粒子。用SEM、XRD、DSC对目标产物进行了表征及性能测试。结果表明,水悬浮法可以使硬脂酸钙和 Estane5703成功包覆在CL-20晶体的表面,CL-20的晶型仍为ε型,说明硬脂酸钙不会改变CL-20主体炸药的晶型。加入硬脂酸钙后,CL-20/Estane复合粒子的特性落高从34.8 cm升至39.8 cm,热稳定性有所改善;当硬脂酸钙的质量分数为0.5%时,CL-20/Estane包覆样品的热爆炸临界温度提高了5.81℃。
以CL-20為主體炸藥、Estane5703為黏結劑、硬脂痠鈣(CaSt2)為增塑劑,採用水懸浮法製備瞭4種複閤粒子。用SEM、XRD、DSC對目標產物進行瞭錶徵及性能測試。結果錶明,水懸浮法可以使硬脂痠鈣和 Estane5703成功包覆在CL-20晶體的錶麵,CL-20的晶型仍為ε型,說明硬脂痠鈣不會改變CL-20主體炸藥的晶型。加入硬脂痠鈣後,CL-20/Estane複閤粒子的特性落高從34.8 cm升至39.8 cm,熱穩定性有所改善;噹硬脂痠鈣的質量分數為0.5%時,CL-20/Estane包覆樣品的熱爆炸臨界溫度提高瞭5.81℃。
이CL-20위주체작약、Estane5703위점결제、경지산개(CaSt2)위증소제,채용수현부법제비료4충복합입자。용SEM、XRD、DSC대목표산물진행료표정급성능측시。결과표명,수현부법가이사경지산개화 Estane5703성공포복재CL-20정체적표면,CL-20적정형잉위ε형,설명경지산개불회개변CL-20주체작약적정형。가입경지산개후,CL-20/Estane복합입자적특성락고종34.8 cm승지39.8 cm,열은정성유소개선;당경지산개적질량분수위0.5%시,CL-20/Estane포복양품적열폭작림계온도제고료5.81℃。
Four kinds of composite particles were prepared by water slurry method using CL-20 as filler,Estane5703 as binder and calcium stearate(CaSt2 )as plasticizer.The CL-20/Estene/CaSt2 composite explosive was characterized by SEM,XRD and DSC.The results show that the CaSt2 and Estane5703 can coat CL-20 successfully,the crystal type of CL-20 was stillε,showing that the CaSt2 can′t change the crystal type of CL-20 main explosive.Compared with CL-20/Estane5703,the characteristic drop height of CL-20/Extane/CaSt2 composite explosive was increased from 34.8 cm to 39.8 cm and the thermal stability improved.The thermal explosion critical tempertature increased by 5 .8 1℃ when the content of CaSt2 was 0 .5%.