CAJ | 학술논문

采用超声波协同Fenton氧化技术对 H MX 生产废水进行处理，考察了超声波频率及功率、Fenton 试剂的投料量、废水的p H 值、反应初始温度等参数对 H MX生产废水中污染物降解的影响。结果表明，反应初始温度及废水的pH 值对降解结果的影响较大。在超声波频率为45 Hz、功率为5 kW／m3、H2 O2与 Fe2＋投料量分别为0．235mol和0．023mol，即n（H2O2）∶n（Fe2＋）＝10∶1，反应初始温度30℃条件下，100mL HMX废水的COD去除率达到80％以上；在 H2 O2投料量较少时超声波协同效应的优势明显，H2 O2与Fe2＋摩尔比越低，超声波协同效应越显著，比单独使用 Fenton 试剂处理的效果好；当 H2 O2与 Fe2＋摩尔比高于10∶1时，超声波的协同效应几乎消失。
채용초성파협동Fenton양화기술대 H MX 생산폐수진행처리，고찰료초성파빈솔급공솔、Fenton 시제적투료량、폐수적p H 치、반응초시온도등삼수대 H MX생산폐수중오염물강해적영향。결과표명，반응초시온도급폐수적pH 치대강해결과적영향교대。재초성파빈솔위45 Hz、공솔위5 kW／m3、H2 O2여 Fe2＋투료량분별위0．235mol화0．023mol，즉n（H2O2）∶n（Fe2＋）＝10∶1，반응초시온도30℃조건하，100mL HMX폐수적COD거제솔체도80％이상；재 H2 O2투료량교소시초성파협동효응적우세명현，H2 O2여Fe2＋마이비월저，초성파협동효응월현저，비단독사용 Fenton 시제처리적효과호；당 H2 O2여 Fe2＋마이비고우10∶1시，초성파적협동효응궤호소실。
The HMX processing wastewater from HMX production was treated by Fenton agent combined with ul-trasonic.The effects of frequency of ultrasonic(US),power of US,dosage of Fenton agent,pH value of waste wa-ter,and the initial reaction temperature on COD removal rate were studied.Results show that the initial reaction temperature and pH value brought more effect on degradation.When the frequency and power of ultrasonic are 45Hzand5kW/m3,dosagesofH2O2andFe2+ are0.235moland0.023mol,that′stosayn(H2O2)∶n(Fe2+)= 10∶1 ,the initial reaction temperature at 30℃,the COD removal rate can reach to 80%.The advantage of synergistic effect caused by ultrasonic method is as follows:the lower the molar ratio of n(H2 O2 )to n(Fe2+),the stronger the effect is.When the ratio of n(H2 O2 )and n(Fe2+)was larger than 10∶1 ,the positive synergistic effect would al-most disappear.