热力发电
熱力髮電
열력발전
THERMAL POWER GENERATION
2015年
7期
18-22,27
,共6页
傅勇强%汪华剑%李奎%陈乃晓%王礼鹏%赵永椿%姚斌
傅勇彊%汪華劍%李奎%陳迺曉%王禮鵬%趙永椿%姚斌
부용강%왕화검%리규%진내효%왕례붕%조영춘%요빈
锅炉%准东煤%碱金属%沾污结渣%灰渣%矿物组分
鍋爐%準東煤%堿金屬%霑汙結渣%灰渣%礦物組分
과로%준동매%감금속%첨오결사%회사%광물조분
boiler%Zhundong coal%alkali metal%fouling and slag%deposition%mineral composition
准东煤易着火、燃尽率高,是优良的动力用煤,但其严重的沾污结渣特性严重影响电厂锅炉安全运行。为此,采用 X 射线衍射仪和环境扫描电子显微镜等,对燃用准东煤电厂锅炉各部位渣样的形貌和矿物组成特征进行了研究。结果表明:锅炉各部位渣样均含有复杂的钠矿物成分,包括钠钙铝氧化物的复杂矿物晶体、钠钾铝硅酸盐、霞石、钠钙铝硅酸盐等;锅炉高温区渣样中识别出大量的非晶组分,这源于各种矿物在高温区的共熔反应;锅炉低温换热面渣样则主要是积灰和沾污样,其含晶形矿物较多,这源于高温区气相组分的冷凝。
準東煤易著火、燃儘率高,是優良的動力用煤,但其嚴重的霑汙結渣特性嚴重影響電廠鍋爐安全運行。為此,採用 X 射線衍射儀和環境掃描電子顯微鏡等,對燃用準東煤電廠鍋爐各部位渣樣的形貌和礦物組成特徵進行瞭研究。結果錶明:鍋爐各部位渣樣均含有複雜的鈉礦物成分,包括鈉鈣鋁氧化物的複雜礦物晶體、鈉鉀鋁硅痠鹽、霞石、鈉鈣鋁硅痠鹽等;鍋爐高溫區渣樣中識彆齣大量的非晶組分,這源于各種礦物在高溫區的共鎔反應;鍋爐低溫換熱麵渣樣則主要是積灰和霑汙樣,其含晶形礦物較多,這源于高溫區氣相組分的冷凝。
준동매역착화、연진솔고,시우량적동력용매,단기엄중적첨오결사특성엄중영향전엄과로안전운행。위차,채용 X 사선연사의화배경소묘전자현미경등,대연용준동매전엄과로각부위사양적형모화광물조성특정진행료연구。결과표명:과로각부위사양균함유복잡적납광물성분,포괄납개려양화물적복잡광물정체、납갑려규산염、하석、납개려규산염등;과로고온구사양중식별출대량적비정조분,저원우각충광물재고온구적공용반응;과로저온환열면사양칙주요시적회화첨오양,기함정형광물교다,저원우고온구기상조분적냉응。
Zhundong coal is easy to burn with a high burn out rate,which is a good coal for power plants. However,the serious fouling and slag occurred on heating surface of the boiler causes serious problems for unit safe operation.In this paper,the slag and deposition samples were collected from a power plant firing Zhundong coal.The X-ray diffraction and environmental scanning electron microscope (ESEM)was ap-plied to analyze the mineral composition of the depositions.The results indicate that,the depositions col-lected from different parts of the boiler have complex Na-containing mineral components,including sodium calcium aluminum oxides mineral crystal,sodium potassium aluminum silicate,nelpheline,and sodium calci-um aluminum silicate.A lot of amorphous components were identified in high temperature area,which is mainly derived from the eutectic reaction of various minerals.Mineral crystals were mainly found in fouling and deposit samples,which was mainly due to the condensation of gas phase.