粘接
粘接
점접
2015年
8期
44-47
,共4页
刘灿%顾继友%郑云武%黄元波%杨晓琴%郑志锋
劉燦%顧繼友%鄭雲武%黃元波%楊曉琴%鄭誌鋒
류찬%고계우%정운무%황원파%양효금%정지봉
多元醇%异氰酸酯%胶粘剂
多元醇%異氰痠酯%膠粘劑
다원순%이청산지%효점제
polyol%isocyanate%adhesive
使用水性异氰酸酯乳液、羧基氧化淀粉、水、淀粉多元醇等材料制备胶粘剂。通过对压制板材力学性能、胶粘剂胶层的FT-IR图谱和热重数据进行分析,探讨了淀粉多元醇加入量对胶粘剂粘接性能的影响。结果表明,多元醇添加量越多胶粘剂中剩余的异氰酸基越少,但胶层的稳定性下降。多元醇添加量为30%、40%时制备的胶粘剂性能较好,用2种胶粘剂压制的胶合板性能达到国家Ⅱ标准。
使用水性異氰痠酯乳液、羧基氧化澱粉、水、澱粉多元醇等材料製備膠粘劑。通過對壓製闆材力學性能、膠粘劑膠層的FT-IR圖譜和熱重數據進行分析,探討瞭澱粉多元醇加入量對膠粘劑粘接性能的影響。結果錶明,多元醇添加量越多膠粘劑中剩餘的異氰痠基越少,但膠層的穩定性下降。多元醇添加量為30%、40%時製備的膠粘劑性能較好,用2種膠粘劑壓製的膠閤闆性能達到國傢Ⅱ標準。
사용수성이청산지유액、최기양화정분、수、정분다원순등재료제비효점제。통과대압제판재역학성능、효점제효층적FT-IR도보화열중수거진행분석,탐토료정분다원순가입량대효점제점접성능적영향。결과표명,다원순첨가량월다효점제중잉여적이청산기월소,단효층적은정성하강。다원순첨가량위30%、40%시제비적효점제성능교호,용2충효점제압제적효합판성능체도국가Ⅱ표준。
In this paper, the starch polyols adhesive was prepacked by using the water-based isocyanate emulsion, carboxylic oxidized starch, water and starch polyols as the raw materials.The effect of starch polyols on the bonding properties of the adhesive was explored. The adhesive was characterized by the mechanical properties of polywood, the FTIR spectra and TGA curves of the cured adhesive. The results showed that with increasing the polyols amount, the isocyanate group content and stability of the cured adhesive were decreased.When the amount of polyols was 30% and 40%, the adhesiveproperties were better and the bonding strength of plywood met the requirement of grade II polywood of standard GB/T9846.3-2004 .