浙江化工
浙江化工
절강화공
ZHEJIANG CHEMICAL INDUSTRY
2015年
8期
5-8,29
,共5页
李峰%王勇%曾昌华%常彦荣
李峰%王勇%曾昌華%常彥榮
리봉%왕용%증창화%상언영
HFC-134a%HFC-125%溶解度%回收
HFC-134a%HFC-125%溶解度%迴收
HFC-134a%HFC-125%용해도%회수
HFC-134a%HFC-125%solubility%recovery
自建装置测定不同温度和压力下HFC-134a和HFC-125在水中溶解度。通过数据分析得出,HFC-134a和HFC-125在水中的溶解度随压力升高显著增加,7000 t/a HFC-134a装置(8000 t/a HFC-125装置)水洗过程中产生的15%混酸(氢氟酸和盐酸)夹带HFC-134a (HFC-125)的年浪费量13.81 t(19.71 t),对工艺操作和回收提出改进意见。
自建裝置測定不同溫度和壓力下HFC-134a和HFC-125在水中溶解度。通過數據分析得齣,HFC-134a和HFC-125在水中的溶解度隨壓力升高顯著增加,7000 t/a HFC-134a裝置(8000 t/a HFC-125裝置)水洗過程中產生的15%混痠(氫氟痠和鹽痠)夾帶HFC-134a (HFC-125)的年浪費量13.81 t(19.71 t),對工藝操作和迴收提齣改進意見。
자건장치측정불동온도화압력하HFC-134a화HFC-125재수중용해도。통과수거분석득출,HFC-134a화HFC-125재수중적용해도수압력승고현저증가,7000 t/a HFC-134a장치(8000 t/a HFC-125장치)수세과정중산생적15%혼산(경불산화염산)협대HFC-134a (HFC-125)적년낭비량13.81 t(19.71 t),대공예조작화회수제출개진의견。
A set of experiment apparatus for determining HFC-134a and HFC-125 solubility in water at different temperatures and pressures was designed. The experimental results showed that the solubility of HFC-134a and HFC-125 in water increased with increasing pressure. 13.81 tons HFC-134a (19.71 tons HFC-125) was wasted owing to the washing process of 7000 tons/year HFC-134a device (8000 tons/year HFC-125) which produced 15%mixed acid, which suggest to improve the process operation and recovery.