绵阳师范学院学报
綿暘師範學院學報
면양사범학원학보
JOURNAL OF MIANYANG NORMAL UNIVERSITY
2015年
8期
73-79
,共7页
刘思曼%文茳%宾胜男%蒋诗
劉思曼%文茳%賓勝男%蔣詩
류사만%문강%빈성남%장시
改性壳聚糖%吸附%锶离子
改性殼聚糖%吸附%鍶離子
개성각취당%흡부%송리자
modified chitosan%adsorPtion%strontium
采用L﹣丙氨酸对壳聚糖进行改性,制备了改性壳聚糖,并研究了改性壳聚糖对水溶液中Sr2+的的吸附性能.结果表明:在吸附时间80 min,吸附温度50℃,吸附剂用量0.1 g ,PH值为10时,L﹣丙氨酸改性壳聚糖对Sr2+吸附的的吸附率可达31.800%,吸附量为11.925 mg/g;L﹣丙氨酸改性壳聚糖微球对高浓度Sr2+的吸附量最大可以达到30.650 mg·g﹣1,吸附率最高可达83.3%;等温吸附结果表明,L﹣丙氨酸改性壳聚糖微球对Sr2+的吸附符合Langmuir等温吸附方程;L﹣丙氨酸改性壳聚糖对Sr2+的吸附过程与准二级动力学具有较高的相关性.
採用L﹣丙氨痠對殼聚糖進行改性,製備瞭改性殼聚糖,併研究瞭改性殼聚糖對水溶液中Sr2+的的吸附性能.結果錶明:在吸附時間80 min,吸附溫度50℃,吸附劑用量0.1 g ,PH值為10時,L﹣丙氨痠改性殼聚糖對Sr2+吸附的的吸附率可達31.800%,吸附量為11.925 mg/g;L﹣丙氨痠改性殼聚糖微毬對高濃度Sr2+的吸附量最大可以達到30.650 mg·g﹣1,吸附率最高可達83.3%;等溫吸附結果錶明,L﹣丙氨痠改性殼聚糖微毬對Sr2+的吸附符閤Langmuir等溫吸附方程;L﹣丙氨痠改性殼聚糖對Sr2+的吸附過程與準二級動力學具有較高的相關性.
채용L﹣병안산대각취당진행개성,제비료개성각취당,병연구료개성각취당대수용액중Sr2+적적흡부성능.결과표명:재흡부시간80 min,흡부온도50℃,흡부제용량0.1 g ,PH치위10시,L﹣병안산개성각취당대Sr2+흡부적적흡부솔가체31.800%,흡부량위11.925 mg/g;L﹣병안산개성각취당미구대고농도Sr2+적흡부량최대가이체도30.650 mg·g﹣1,흡부솔최고가체83.3%;등온흡부결과표명,L﹣병안산개성각취당미구대Sr2+적흡부부합Langmuir등온흡부방정;L﹣병안산개성각취당대Sr2+적흡부과정여준이급동역학구유교고적상관성.
Ⅰn this PaPer,an efficient Procedure to modify chitosan was carried out by the reaction of alanine and chitosan. The adsorPtion behavior of Sr2+ by modified chitosan was investigated. On the condition of the ad-sorPtion time 80 mins,the adsorPtion temPerature 40 ℃,the modified chitosan'squantity 0. 1 g,and the PH value 10,the adsorPtion rate of Sr2+ was uP to 31. 800%,and the adsorPtion quantity was uP to 11. 925 mg/g. The lar-gest adsorPtion quantity was uP to 30. 650 mg/g,and the largest adsorPtion rate was uP to 83. 3 %. The isother-mal showed that the adsorPtion of chitosan modified with alanine for strontiumin accordance with Langmuir isother-mal adsorPtion equation. The adsorPtion Process kinetics accords to the second order equation.