有色金属科学与工程
有色金屬科學與工程
유색금속과학여공정
JIANGXI NONFERROUS METALS
2015年
4期
52-57
,共6页
陈鹏%钟盛文%梅文捷%刘熙林%金柱%胡经纬
陳鵬%鐘盛文%梅文捷%劉熙林%金柱%鬍經緯
진붕%종성문%매문첩%류희림%금주%호경위
气氛%LiNi0.7Mn0.3O2%无钴%共沉淀%锂离子电池
氣氛%LiNi0.7Mn0.3O2%無鈷%共沉澱%鋰離子電池
기분%LiNi0.7Mn0.3O2%무고%공침정%리리자전지
atmosphere%LiNi0.7Mn0.3O2%cobalt free%co-precipitation%lithium ion battery
采用共沉淀-高温固相法,控制烧结气氛制备出LiNi0.7Mn0.3O2.借助扫描电子显微镜(SEM)、X射线衍射分析(XRD)、氧气分析仪、电池测试系统及电化学工作站对不同气氛条件下制备的LiNi0.7Mn0.3O2进行结构、形貌、固相反应过程氧气浓度变化、电性能和内阻的表征.研究结果表明,烧结过程存在2次明显吸氧阶段且全程通高纯氧制备的材料有更好的球形度,层状结构更完整,充放电性能及循环稳定性都更好,内阻也较小;在2.75~4.35 V电压范围内,以0.2 C进行充放电,其首次放电比容量高达191.0 mAh/g,70周循环后容量保持率为95.2%.烧结过程中由一种气氛切换为另一种气氛比烧结全程不通气或通空气所制备材料的性能差,但其首次比容量都低于184.0 mAh/g,70周循环后的容量保持率也都不足85.0%.
採用共沉澱-高溫固相法,控製燒結氣氛製備齣LiNi0.7Mn0.3O2.藉助掃描電子顯微鏡(SEM)、X射線衍射分析(XRD)、氧氣分析儀、電池測試繫統及電化學工作站對不同氣氛條件下製備的LiNi0.7Mn0.3O2進行結構、形貌、固相反應過程氧氣濃度變化、電性能和內阻的錶徵.研究結果錶明,燒結過程存在2次明顯吸氧階段且全程通高純氧製備的材料有更好的毬形度,層狀結構更完整,充放電性能及循環穩定性都更好,內阻也較小;在2.75~4.35 V電壓範圍內,以0.2 C進行充放電,其首次放電比容量高達191.0 mAh/g,70週循環後容量保持率為95.2%.燒結過程中由一種氣氛切換為另一種氣氛比燒結全程不通氣或通空氣所製備材料的性能差,但其首次比容量都低于184.0 mAh/g,70週循環後的容量保持率也都不足85.0%.
채용공침정-고온고상법,공제소결기분제비출LiNi0.7Mn0.3O2.차조소묘전자현미경(SEM)、X사선연사분석(XRD)、양기분석의、전지측시계통급전화학공작참대불동기분조건하제비적LiNi0.7Mn0.3O2진행결구、형모、고상반응과정양기농도변화、전성능화내조적표정.연구결과표명,소결과정존재2차명현흡양계단차전정통고순양제비적재료유경호적구형도,층상결구경완정,충방전성능급순배은정성도경호,내조야교소;재2.75~4.35 V전압범위내,이0.2 C진행충방전,기수차방전비용량고체191.0 mAh/g,70주순배후용량보지솔위95.2%.소결과정중유일충기분절환위령일충기분비소결전정불통기혹통공기소제비재료적성능차,단기수차비용량도저우184.0 mAh/g,70주순배후적용량보지솔야도불족85.0%.
The LiNi0.7Mn0.3O2 cathode material was synthesized under different sintering atmosphere via co-precipitation and high temperature sintering method. The morphology, crystal structure, oxygen concentration, electrochemical performance and electrochemical impedance spectroscopy for LiNi 0.7Mn0.3O2 cathode material were characterized and tested by means of scanning electron microscopy (SEM), powder X-ray diffraction (XRD), oxygen analyzer, galvanostatic charge-discharge tests and electrochemical workstation. The results show that under the condition of whole sintering time in high purity oxygen atmosphere, the obtained material exhibits the best spherical morphology, the most complete layer structure, the best electrochemical performance and the smallest internal impedance. The initial discharge specific capacity of the material is as high as 191.0 mAh/g at 0.2 C within the voltage range of 2.75~4.35 V, the capacity retention ratio is 95.2 %after 70 cycles. But when the materials are synthesized in other sintering atmosphere, the initial discharge specific capacity are all below 184.0 mAh/g, and the capacity retention ratio are also all below 85 % after 70 cycles.