CAJ | 학술논문

为实现熔盐电解法制备稀土合金工艺大型化、低能耗和高效性，采用25 kA电解电流在氟化物体系中的熔盐电解工艺制备稀土镨钕合金。通过工业实践，探究了电解过程中电解槽结构、电解温度、电流密度、电解质组分、搅炉操作及坩埚材质对电解产品纯度的影响。实验研究确立了25 kA熔盐电解法制备稀土镨钕合金有效控制非稀土杂质含量的工艺参数。
위실현용염전해법제비희토합금공예대형화、저능모화고효성，채용25 kA전해전류재불화물체계중적용염전해공예제비희토보녀합금。통과공업실천，탐구료전해과정중전해조결구、전해온도、전류밀도、전해질조분、교로조작급감과재질대전해산품순도적영향。실험연구학립료25 kA용염전해법제비희토보녀합금유효공제비희토잡질함량적공예삼수。
In order to achieve the large-scale, low-energy and high efficiency in the preparation of the rare earth alloy by the molten salt electrolysis, 25 kA electrolysis current was adopted in the preparation of praseodymium neodymium alloys in fluoride salt system. Through the industrial practice, the impacts of electrolytic tank structure, electrolytic temperature, and current density, electrolyte composition, stirring furnace operation and crucible material on the quality of electrolytic products were explored. Experiment establishes the technologic parameter for the effective control of non-rare earth impurity in the preparation of praseodymium neodymium alloy by 25 kA molten salt electrolysis.