长春理工大学学报(自然科学版)
長春理工大學學報(自然科學版)
장춘리공대학학보(자연과학판)
JOURNAL OF CHANGCHUN UNIVERSITY OF SCIENCE AND TECHNOLOGY(NATURAL SCIENCE EDITION)
2015年
4期
82-86
,共5页
王淑亚%姜禹竹%赵莹%董玮利%万玉春%宋博
王淑亞%薑禹竹%趙瑩%董瑋利%萬玉春%宋博
왕숙아%강우죽%조형%동위리%만옥춘%송박
蚜虫%石蜡%红外吸收光谱%荧光光谱
蚜蟲%石蠟%紅外吸收光譜%熒光光譜
아충%석사%홍외흡수광보%형광광보
aphid%paraffin%infrared absorption spectroscopy%fluorescence spectrum
针对不可再生石油资源日益减少的问题,开发和利用天然生物材料替代短缺资源具有十分重要的意义。采用SEM、红外吸收光谱、XRD、荧光光谱等测试方法对东北地区生长的有翅蚜虫的自然巢穴(俗称小咬窝)材料进行了结构表征和光谱分析,发现该巢穴是一种新型自然生物石蜡。通过SEM分析确定该新型石蜡的结构为空心丝状物;红外吸收光谱表明该新型石蜡由饱和或不饱和的长链烃、长链脂肪醇、以及带有芳香烃及其衍生物构成;该新型石蜡XRD衍射图与标准PDF卡PDF#40-1995(正链烷烃,(CH2)x)匹配,并选用性质相似的工业蜡的XRD作对比进一步确定其性质,得出小咬窝原材料的主峰位置(21.694?,24.063?)和工业蜡的主峰位置(21.753?,24.076?)非常接近,可确定物相是相同的,从而确定小咬窝为一种天然生物蜡;对小咬窝原材料的发射光谱和激发光谱分析,获得发光波长范围为400~460nm,但发光强度非常微弱。
針對不可再生石油資源日益減少的問題,開髮和利用天然生物材料替代短缺資源具有十分重要的意義。採用SEM、紅外吸收光譜、XRD、熒光光譜等測試方法對東北地區生長的有翅蚜蟲的自然巢穴(俗稱小咬窩)材料進行瞭結構錶徵和光譜分析,髮現該巢穴是一種新型自然生物石蠟。通過SEM分析確定該新型石蠟的結構為空心絲狀物;紅外吸收光譜錶明該新型石蠟由飽和或不飽和的長鏈烴、長鏈脂肪醇、以及帶有芳香烴及其衍生物構成;該新型石蠟XRD衍射圖與標準PDF卡PDF#40-1995(正鏈烷烴,(CH2)x)匹配,併選用性質相似的工業蠟的XRD作對比進一步確定其性質,得齣小咬窩原材料的主峰位置(21.694?,24.063?)和工業蠟的主峰位置(21.753?,24.076?)非常接近,可確定物相是相同的,從而確定小咬窩為一種天然生物蠟;對小咬窩原材料的髮射光譜和激髮光譜分析,穫得髮光波長範圍為400~460nm,但髮光彊度非常微弱。
침대불가재생석유자원일익감소적문제,개발화이용천연생물재료체대단결자원구유십분중요적의의。채용SEM、홍외흡수광보、XRD、형광광보등측시방법대동북지구생장적유시아충적자연소혈(속칭소교와)재료진행료결구표정화광보분석,발현해소혈시일충신형자연생물석사。통과SEM분석학정해신형석사적결구위공심사상물;홍외흡수광보표명해신형석사유포화혹불포화적장련경、장련지방순、이급대유방향경급기연생물구성;해신형석사XRD연사도여표준PDF잡PDF#40-1995(정련완경,(CH2)x)필배,병선용성질상사적공업사적XRD작대비진일보학정기성질,득출소교와원재료적주봉위치(21.694?,24.063?)화공업사적주봉위치(21.753?,24.076?)비상접근,가학정물상시상동적,종이학정소교와위일충천연생물사;대소교와원재료적발사광보화격발광보분석,획득발광파장범위위400~460nm,단발광강도비상미약。
To counter the problem of non-renewable dwindling oil resources,the development and utilization of natural biologi-cal material was great significant to replace shortage of alternative resources. In this article, SEM, infrared absorption spectroscopy, XRD and fluorescence spectrum were used to test structure characterization and spectral analyses of winged aphid natural nests (commonly known as stinger nest) material that grow in the Northeast China. The nest was a new type of natural biological paraffin material. Through SEM analyzing, the structure of the new type of paraffin was the hollow filaments. Infrared absorption spectra show that the new type of paraffin was formed by saturated or un-saturated long-chain hydrocarbons, long chain fatty alcohols, and aromatic hydrocarbons and their derivatives. Its XRD diffraction pattern matched with standard PDF card PDF#40-1995(paraffin,(CH2)x). Choosing the industrial wax to make a contrast, the main peak position of the raw material (21.694?,24.063?) was very close to industrial wax (21.753?,24.076?). It could determine that their phase was the same and the stinger nest was a kind of natural biologi-cal wax. Through the emission spectrum and excitation spectrum of raw materials, luminous range was 400nm-460nm, but the luminous intensity was very weak.