CAJ | 학술논문

采用模板法，将3,4-二氨基苯甲酸、水杨醛和钴盐以1：2：1比例混合制备席夫碱合钴配合物,并对其进行了红外表征紫外及、摩尔电导和磁性等性质测定。数据分析结果表明：通过席夫碱合钴红外谱图和摩尔电导结果的对比和分析，表明金属与 N 原子进行了配位，钴盐中的阴离子并未参与配位；通过磁化率的测定，得出席夫碱合钴配合物中钴的单电子数为1，进而可以推测该配合物的分子构型是平面四边形。
채용모판법，장3,4-이안기분갑산、수양철화고염이1：2：1비례혼합제비석부감합고배합물,병대기진행료홍외표정자외급、마이전도화자성등성질측정。수거분석결과표명：통과석부감합고홍외보도화마이전도결과적대비화분석，표명금속여 N 원자진행료배위，고염중적음리자병미삼여배위；통과자화솔적측정，득출석부감합고배합물중고적단전자수위1，진이가이추측해배합물적분자구형시평면사변형。
Cobalt(II) schiff base complexes with 3,4-(bis(salicylaldehyde)amino)benzoic acid were synthesized by template method. The complexes were characterized by IR, UV-Vis, molar conductivity and magnetic properties. The results show that, cobalt salt anion is not involved in the complexes; it is found that there is only one unpaired electron in the complex, so it is proved the structure of the complex is square planar.