安徽大学学报（自然科学版）
安徽大學學報（自然科學版）
안휘대학학보（자연과학판）
JOURNAL OF ANHUI UNIVERSITY(NATURAL SCIENCES EDITION)
2015年
5期
81-88
,共8页
AAO模板%纳米管阵列%Eu3+掺杂%荧光性能
AAO模闆%納米管陣列%Eu3+摻雜%熒光性能
AAO모판%납미관진렬%Eu3+참잡%형광성능
AAO template%nanotube arrays%Eu3+ doped%luminescence property
以Ln（NO3）3·6H2 O（Ln＝La ，Y ，Eu）和NaF为原料，采用AAO模板制备一维Lax Y1‐x F3纳米管、纳米线阵列。使用XRD、EDS、SEM和TEM分别对样品的结构、组成与形貌进行表征，并研究不同摩尔分数Eu3＋掺杂的Lax Y1‐x F3纳米管的荧光性能。荧光光谱结果表明：Lax Y1‐x F3：Eu3＋的发射光谱均由在593 nm （5 D0→7 F1）和711 nm （5 D0→7 F4）两组线状峰构成。样品的发光强度随Eu3＋的摩尔分数的增大而存在一个极大值。实验结果表明，6％ Eu3＋掺杂的Lax Y1‐x F3纳米管的荧光性能最优。
以Ln（NO3）3·6H2 O（Ln＝La ，Y ，Eu）和NaF為原料，採用AAO模闆製備一維Lax Y1‐x F3納米管、納米線陣列。使用XRD、EDS、SEM和TEM分彆對樣品的結構、組成與形貌進行錶徵，併研究不同摩爾分數Eu3＋摻雜的Lax Y1‐x F3納米管的熒光性能。熒光光譜結果錶明：Lax Y1‐x F3：Eu3＋的髮射光譜均由在593 nm （5 D0→7 F1）和711 nm （5 D0→7 F4）兩組線狀峰構成。樣品的髮光彊度隨Eu3＋的摩爾分數的增大而存在一箇極大值。實驗結果錶明，6％ Eu3＋摻雜的Lax Y1‐x F3納米管的熒光性能最優。
이Ln（NO3）3·6H2 O（Ln＝La ，Y ，Eu）화NaF위원료，채용AAO모판제비일유Lax Y1‐x F3납미관、납미선진렬。사용XRD、EDS、SEM화TEM분별대양품적결구、조성여형모진행표정，병연구불동마이분수Eu3＋참잡적Lax Y1‐x F3납미관적형광성능。형광광보결과표명：Lax Y1‐x F3：Eu3＋적발사광보균유재593 nm （5 D0→7 F1）화711 nm （5 D0→7 F4）량조선상봉구성。양품적발광강도수Eu3＋적마이분수적증대이존재일개겁대치。실험결과표명，6％ Eu3＋참잡적Lax Y1‐x F3납미관적형광성능최우。
The one‐dimensional LaxY1‐xF3 nanotube and nanowire arrays were synthesized with Ln(NO3 )3 (Ln=La ,Y ,Eu)and NaF solution via anodic aluminum oxide (AAO) template . The structure ,composition and morphology of LaxY1‐xF3 nanotube arrays were characterized using XRD ,EDS ,SEM and TEM ,respectively .The fluorescence properties of Lax Y1‐x F3 :Eu3+ nanotubes were also investigated by fluorescence spectrophotometer ,and the results indicated that there were two typical linear emission peaks near 593 nm (5D0 → 7 F1 ) and 711 nm (5D0 → 7F4 ) ,respectively .The emission intensities of the samples increased with the increase of the mole fraction of Eu3+ ion .When the doping Eu3+ ion was 6% in mole ratio , the luminescence intensity of LaxY1‐xF3 :Eu3+ nanotubes was the maximum .
