CAJ | 학술논문

采用自制的曝气反应器，探讨了在传统的铁碳内电解的基础上，加入第三种阴极材料镍构成三元内电解体系处理模拟染料废水———活性艳红X－3B。考查了曝气类型、曝气量、废水pH值和投料质量比对降解效果的影响。实验表明，在最佳条件下：曝气类型为空气，曝气量为60 L／h， pH为4，投料中的mFe：mNi：mC＝3：2：4（质量比），反应270 min后，活性艳红X－3B的去除率可以达到87.2％， TOC去除率为63.5％，优于传统二元内电解法。另外，紫外—可见光光谱分析表明活性艳红X－3B的分子结构在反应过程中遭到了破坏，可能生成了一些小分子的中间产物。
채용자제적폭기반응기，탐토료재전통적철탄내전해적기출상，가입제삼충음겁재료얼구성삼원내전해체계처리모의염료폐수———활성염홍X－3B。고사료폭기류형、폭기량、폐수pH치화투료질량비대강해효과적영향。실험표명，재최가조건하：폭기류형위공기，폭기량위60 L／h， pH위4，투료중적mFe：mNi：mC＝3：2：4（질량비），반응270 min후，활성염홍X－3B적거제솔가이체도87.2％， TOC거제솔위63.5％，우우전통이원내전해법。령외，자외—가견광광보분석표명활성염홍X－3B적분자결구재반응과정중조도료파배，가능생성료일사소분자적중간산물。
Based on the traditional Fe/C internal micro-electrolysis , the ternary internal micro-electrolysis system was constituted by adding the third material Ni on treating the simulant dyeing wastewater -reactive brilliant red X-3 B dying wastewater with using homemade reactor.The aeration style , the aeration amount , the pH of wastewater and the mass ratio were investigated.The results showed that the aeration ternary internal micro-electrolysis system was much better than dual internal micro-electrolysis on the condition that the mass ratio of ZVI , active carbon and Nickel powder was 3:2:4, the initial pH was 4, the aeration amount was 60 L/h, the degradation rate of reactive brilliant red X-3B reached 87.2%and the degradation rate of TOC was 63.5%within 270 min reaction time.In addition , the analysis of UV-Vis showed that the molecular structure of the reactive brilliant red X -3 B was destroyed , it maybe generate many small molecules intermediate product.