工业催化
工業催化
공업최화
INDUSTRIAL CATALYSIS
2015年
8期
641-644
,共4页
石油化学工程%裂解重 C ﹢9 馏分%一段加氢%YN - 1 型镍系催化剂
石油化學工程%裂解重 C ﹢9 餾分%一段加氫%YN - 1 型鎳繫催化劑
석유화학공정%렬해중 C ﹢9 류분%일단가경%YN - 1 형얼계최화제
petroleUm chemical engineering%heavy C ﹢9 cUt pyrolysis%first stage hydrogenation%YN-1 nickel based catalyst
介绍了中国石化催化剂北京燕山分公司的裂解重 C ﹢9馏分一段加氢工况,采用了低压、低空速、高氢油比和高循环比的加氢工艺。依据工业装置原料性质、反应温度和反应器进、出口压力变化情况,统计分析了使用 YN -1型镍系催化剂没有经过再生进行一段加氢产品的溴价和双烯含量变化,工业应用结果表明,YN -1型镍系催化剂具有优异的加氢活性和长周期运行的稳定性。
介紹瞭中國石化催化劑北京燕山分公司的裂解重 C ﹢9餾分一段加氫工況,採用瞭低壓、低空速、高氫油比和高循環比的加氫工藝。依據工業裝置原料性質、反應溫度和反應器進、齣口壓力變化情況,統計分析瞭使用 YN -1型鎳繫催化劑沒有經過再生進行一段加氫產品的溴價和雙烯含量變化,工業應用結果錶明,YN -1型鎳繫催化劑具有優異的加氫活性和長週期運行的穩定性。
개소료중국석화최화제북경연산분공사적렬해중 C ﹢9류분일단가경공황,채용료저압、저공속、고경유비화고순배비적가경공예。의거공업장치원료성질、반응온도화반응기진、출구압력변화정황,통계분석료사용 YN -1형얼계최화제몰유경과재생진행일단가경산품적추개화쌍희함량변화,공업응용결과표명,YN -1형얼계최화제구유우이적가경활성화장주기운행적은정성。
The operation process of heavy C ﹢9 cUt pyrolysis in the first stage hydrogenation Unit in Beijing Yansan Branch of Sinopec Catalyst Company Under the condition of low pressUre,low space velocity,high hydrogen / oil ratio,and high recycling ratio was introdUced. Based on the condition change of feed proper-ties,reaction temperatUres and pressUre drop of reactor inlet and oUtlet over YN-1 nickel based catalyst withoUt regeneration,the change of bromine valence and diene contents of the first stage hydrogenation prodUct were statistically analyzed. The commercial application resUlts showed that YN-1 nickel based cat-alyst had excellent hydrogenation activity and stability dUring the long period operation.