CAJ | 학술논문

ZSM -5分子筛由于其独特的骨架结构和酸性等特性，广泛用于石油化工领域。在催化裂化过程中，ZSM -5分子筛及其改性产品经常被加入以提高产品性能和选择性，特别是提升汽油辛烷值，增产丙烯等高附加值化工原料。通过严格控制化学合成与制备条件，制备具有相同晶体形貌、硅铝物质的量比约100和晶粒尺寸2.5μm 至100 nm 系列分子筛。研究分子筛的酸性、晶粒尺寸和比表面积对分子筛热稳定性、水热稳定性、活性和孔道等的影响。制成 FCC 助剂后，利用 ACE和炼油厂原料考察 FCC 助剂在催化裂化反应中的性能，结果表明，硅铝物质的量比为80~100和晶粒尺寸为2.5μm 的 ZSM -5分子筛，可以获得最佳的丙烯选择性。
ZSM -5분자사유우기독특적골가결구화산성등특성，엄범용우석유화공영역。재최화열화과정중，ZSM -5분자사급기개성산품경상피가입이제고산품성능화선택성，특별시제승기유신완치，증산병희등고부가치화공원료。통과엄격공제화학합성여제비조건，제비구유상동정체형모、규려물질적량비약100화정립척촌2.5μm 지100 nm 계렬분자사。연구분자사적산성、정립척촌화비표면적대분자사열은정성、수열은정성、활성화공도등적영향。제성 FCC 조제후，이용 ACE화련유엄원료고찰 FCC 조제재최화열화반응중적성능，결과표명，규려물질적량비위80~100화정립척촌위2.5μm 적 ZSM -5분자사，가이획득최가적병희선택성。
ZSM-5 molecUlar sieve is widely Used in the petrochemical field dUe to its special framework strUctUre and UniqUe acidity. ZSM-5 molecUlar sieve and it’s modified prodUcts are freqUently applied in FCC process in order to improve the properties of and the selectivity to the prodUcts,enhance the octane nUmber of gasoline and increase propene yield. A series of ZSM-5 molecUlar sieves with the same crystal morphology,silica / alUmina molar ratio of aboUt 100 and particle size of 2. 5 μm - 100 nm were prepared by adjUsting the synthetic condition. The inflUence of acidity,particle size and specific sUrface area of the molecUlar sieves on their thermal stability,hydrothermal stability,activity and poroUs properties was inves-tigated. FCC additives were prepared,and then their properties for raw material catalytic cracking of oil refinery were evalUated by ACE. The resUlts showed that ZSM-5 molecUlar sieve with silica / alUmina molar ratio of 80 - 100 and particle size of 2. 5 μm possessed the optimal selectivity to propene dUring FCC reaction.