CAJ | 학술논문

在连续微反装置中,氢气分压9.0 M Pa,体积空速(LHSV)0.6~3-h 1条件下,以正十六烷为模型化合物评价了两种催化剂的加氢异构性能。研究了不同催化剂的正十六烷加氢异构反应动力学,并建立了相应的反应网络。研究结果表明:在两种不同助剂和载体的催化剂A、B作用下正十六烷的加氢异构反应网络不同,催化剂B的反应活性和异构产物的选择性较催化剂A高,更有利于生产高质量的润滑油基础油。
재련속미반장치중,경기분압9.0 M Pa,체적공속(LHSV)0.6~3-h 1조건하,이정십륙완위모형화합물평개료량충최화제적가경이구성능。연구료불동최화제적정십륙완가경이구반응동역학,병건립료상응적반응망락。연구결과표명:재량충불동조제화재체적최화제A、B작용하정십륙완적가경이구반응망락불동,최화제B적반응활성화이구산물적선택성교최화제A고,경유리우생산고질량적윤활유기출유。
n-Hexadecane was selected as model compound and investigated in a micro continuous reactor in the present of two kinds of catalysts.Experiments were conducted at the conditions of hydrogen pressure 9.0 MPa,LHSV ranging from 0.6 to 3 h~(-1),and different reaction temperature for different catalysts.Then,hydroisomerization pathways and kinetics of normal hexadecane were established on the base of productions yields for both catalysts.The results show that reaction networks are different in the presence of cat...