华东理工大学学报:社会科学版
華東理工大學學報:社會科學版
화동리공대학학보:사회과학판
SOCIAL SCIENCES JOURNAL OF ECUST
2004年
5期
~
,共null页
代培刚 张惠跃 王昕 施力
代培剛 張惠躍 王昕 施力
대배강 장혜약 왕흔 시력
催化剂 烯烃 芳烃 溴值
催化劑 烯烴 芳烴 溴值
최화제 희경 방경 추치
catalyst; olefins; aromatic hydrocarbons; bromine index;
以分子筛为活性组分,与一定比例的载体混合后制成催化剂并评价了该类催化剂的活性和稳定性,用吡啶FT-IR测定了催化剂的表面酸性;同时探讨了催化剂表面酸性与催化剂活性之间的关系,发现催化剂的活性不仅与总酸量有关,还和B酸量与L酸量之比有关。当催化剂上B酸量与L酸量达到恰当比例时,催化剂的活性最好。
以分子篩為活性組分,與一定比例的載體混閤後製成催化劑併評價瞭該類催化劑的活性和穩定性,用吡啶FT-IR測定瞭催化劑的錶麵痠性;同時探討瞭催化劑錶麵痠性與催化劑活性之間的關繫,髮現催化劑的活性不僅與總痠量有關,還和B痠量與L痠量之比有關。噹催化劑上B痠量與L痠量達到恰噹比例時,催化劑的活性最好。
이분자사위활성조분,여일정비례적재체혼합후제성최화제병평개료해류최화제적활성화은정성,용필정FT-IR측정료최화제적표면산성;동시탐토료최화제표면산성여최화제활성지간적관계,발현최화제적활성불부여총산량유관,환화B산량여L산량지비유관。당최화제상B산량여L산량체도흡당비례시,최화제적활성최호。
The catalyst was made of zeolite as the active component with boehmite as the carrier. Its activity of olefins removal was tested and solid catalyst surface acidity was measured by pyridine FT-IR. The relation between its activity and its surface acid sites was also investigated, which shows that the activitywas affected not only by the amount of acid sites but also by the proportion between B acid sites and L acid sites. The activity of the catalyst was the best when the proportion between B acid sites and...