洛阳师范学院学报
洛暘師範學院學報
락양사범학원학보
Journal of Luoyang Teachers College
2008年
5期
~
,共null页
邻苯二胺 氮（杂）蒽 晶体结构 超分子
鄰苯二胺 氮（雜）蒽 晶體結構 超分子
린분이알 담（잡）은 정체결구 초분자
1; 2-phenylenediamine; naphthazine; crystal structure; supramolecular;
一个新的三维超分子化合物(C12N4H10)[(C12N4H11)Cl](H2O)7通过溶液法合成。该化合物为三斜晶系,P-1空间群,晶胞参数:a=7.1350(14),b=12.594(2),c=16.210(3),α=82.675(3)°,β=78.588(3)°,γ=84.198(3)°,V=1411.8(5)3,Z=2,Dc=1.372Mg.m-3,F(000)=616,Mr=583.05,最终偏离因子R1=0.0798,wR2=0.2100。化合物通过O-H…O,O-H…Cl,O-H…N,N-H…O和N-H…Cl多种氢键作用连接成三维超分子结构。
一箇新的三維超分子化閤物(C12N4H10)[(C12N4H11)Cl](H2O)7通過溶液法閤成。該化閤物為三斜晶繫,P-1空間群,晶胞參數:a=7.1350(14),b=12.594(2),c=16.210(3),α=82.675(3)°,β=78.588(3)°,γ=84.198(3)°,V=1411.8(5)3,Z=2,Dc=1.372Mg.m-3,F(000)=616,Mr=583.05,最終偏離因子R1=0.0798,wR2=0.2100。化閤物通過O-H…O,O-H…Cl,O-H…N,N-H…O和N-H…Cl多種氫鍵作用連接成三維超分子結構。
일개신적삼유초분자화합물(C12N4H10)[(C12N4H11)Cl](H2O)7통과용액법합성。해화합물위삼사정계,P-1공간군,정포삼수:a=7.1350(14),b=12.594(2),c=16.210(3),α=82.675(3)°,β=78.588(3)°,γ=84.198(3)°,V=1411.8(5)3,Z=2,Dc=1.372Mg.m-3,F(000)=616,Mr=583.05,최종편리인자R1=0.0798,wR2=0.2100。화합물통과O-H…O,O-H…Cl,O-H…N,N-H…O화N-H…Cl다충경건작용련접성삼유초분자결구。
A novel supramolecular compound(C12N4H10) [(C12N4H11)Cl](H2O)7 have been synthesized by solution method and structurally characterized by X-ray diffraction analysis.It crystallizes in the thrclinic system,space group P-1,with a=7.1350(14),b=12.594(2),c=16.210(3),α=82.675(3)°,β=78.588(3)°,γ=84.198(3) °,V=1411.8(5)3,Z=2,Dc=1.372Mg.m-3,F(000)=616,Mr=583.05,R1=0.0798,wR2=0.2100.X-ray diffraction analysis reveals that a 3D extended supermolecular network was formed though O-H…O,O-H…Cl,O-H…N,N-H…O and N-H…Cl ...
