CAJ | 학술논문

采用Fourier变换红外吸收光谱和X射线粉晶衍射技术对四川石棉县蛇纹石猫眼进行了研究。红外吸收光谱结果表明：四川蛇纹石猫眼可分为纤蛇纹石和叶蛇纹石两种类型，两者在（960—1100）cm^-1和（3600—3690）cm^-1的范围内由Si-O伸缩振动的E1类振动和OH伸缩振动表现出的红外谱带分裂强度及谱带特征存在明显的差异。在（960—1100）cm^-1间：纤蛇蚊石的红外光谱分裂成三个明显的谱带，而叶蛇纹石在此区间只有两条谱带。在570cm^-1附近的红外谱带以肩状出现；OH伸缩振动区：纤蛇蚊石出现两条红外谱带，而叶蛇蚊石只出现一条红外谱带。X射线粉晶衍射结果表明：叶蛇蚊石具有d202=0．2522nm（I／I0=19）和d203=0．2430nm（I／I0=18）的特征谱线，而纤蛇纹石则具有d202、006=0．2446nm（I／I0=29）的特征谱线，d020〉0．245nm近0．249nm的特征谱线缺失。
채용Fourier변환홍외흡수광보화X사선분정연사기술대사천석면현사문석묘안진행료연구。홍외흡수광보결과표명：사천사문석묘안가분위섬사문석화협사문석량충류형，량자재（960—1100）cm^-1화（3600—3690）cm^-1적범위내유Si-O신축진동적E1류진동화OH신축진동표현출적홍외보대분렬강도급보대특정존재명현적차이。재（960—1100）cm^-1간：섬사문석적홍외광보분렬성삼개명현적보대，이협사문석재차구간지유량조보대。재570cm^-1부근적홍외보대이견상출현；OH신축진동구：섬사문석출현량조홍외보대，이협사문석지출현일조홍외보대。X사선분정연사결과표명：협사문석구유d202=0．2522nm（I／I0=19）화d203=0．2430nm（I／I0=18）적특정보선，이섬사문석칙구유d202、006=0．2446nm（I／I0=29）적특정보선，d020〉0．245nm근0．249nm적특정보선결실。
FTIR absorption spectra and XRD were used to study serpentine cat＇s eye from Sichuan province in this paper. The results indicate that serpentine cat＇s eyes includes two types： chrysotile and antigorite, which have the characteristic bands in the Si - O Stretching vibration region around （960 - 1100 ） cm^-1 and OH Stretching vibration region around （ 3600 - 3690 ） cm^-1 respectively. Around （ 960 - 1100 ） cm^-1, chrysotile displays three bands of absorption, while antigorite only has two bands. Upon 570cm^-1, antigorite shows a shoulder absorption band. XRD shows that antigorite is characterized by the lines d202 =0. 2522nm （I/I0= 19） and d2o3 =0. 2430nm （I/I0 = 18 ） ,while chrysotile only has the line d202,006 = 0. 2446nm .（ I/I0 =29） without the line near d020 =0. 250nm.