CAJ | 학술논문

为了进一步讨论明清两代祭红釉的发展沿革，用探针型能量色散X荧光光谱技术测定了10片明永乐祭红釉和胎的化学组成，并结合已发表的相关数据，进行了对明清期间祭红釉和胎的对比研究。结果表明，明代（永乐-宣德—万历）的祭红釉相比于清代（康熙—雍正-乾隆）的R2O＋RO（wt％）平均值约低20％，RO／R2O（mol/mol）平均值约低45％，RO2／R2O2，（mol/mol）平均值约高34％。明代永乐和宣德的祭红釉胎式分布RO：（m01）值均大于5．8，而清代样品均小于5．4。明清两代祭红釉化学组成的突然变化（shift），可能暗示明代的制釉工艺在清代已经失传，而在清代则白行发展起来。
위료진일보토론명청량대제홍유적발전연혁，용탐침형능량색산X형광광보기술측정료10편명영악제홍유화태적화학조성，병결합이발표적상관수거，진행료대명청기간제홍유화태적대비연구。결과표명，명대（영악-선덕—만력）적제홍유상비우청대（강희—옹정-건륭）적R2O＋RO（wt％）평균치약저20％，RO／R2O（mol/mol）평균치약저45％，RO2／R2O2，（mol/mol）평균치약고34％。명대영악화선덕적제홍유태식분포RO：（m01）치균대우5．8，이청대양품균소우5．4。명청량대제홍유화학조성적돌연변화（shift），가능암시명대적제유공예재청대이경실전，이재청대칙백행발전기래。
To better understand the development of sacrificial red glazes during the Ming and Qing Dynasties, the chemical compositions of 10 pieces of Yongle sacrificial red glaze porcelains in Ming Dynasty were determined, using the microprobe EDXRF. Combined with previously published data, the sacrificial red glazes and bodies made during Ming and Qing Dynasties were compared. Results showed that the mean values of RO ＋ R20 （ wt% ）, in the sacrificial red glaze from Yongle, Xuande, and Wanli porcelains of the Ming Dynasty were 20% lower than that in the Kangxi, Yongzheng, and Qianlong porcelains of the Qing Dynasty, whereas its mean value of RO/R2O （ mol/ mol） was 45% less and the mean value of RO2/R2O3 （mol/mol） was 34% higher. The RO2 （mol） values of Yongle, Xuande, and Wanli porcelains of the Ming Dynasty were all above 5.8 but these of Qing Dynasty ones were all below 5.4. The changes in chemical composition suggest that the process for making the sacrificial red glaze in the Ming Dynasty was lost and a new process was created in the Qing Dynasty.