CAJ | 학술논문

综述了不同条件下4-羟基香豆素类化合物与对醌的Michael加成反应及其反应机理．在丙酮-水中，4-羟基香豆素类化合物与1，4-苯醌反应生成2，3-二取代-1，4-苯醌，与1，4-萘醌反应生成2，3-二取代-1，4-蔡醌．在丙酮-水中，吡啶存在下，4-羟基香豆素类化合物与1，4-苯醌反应生成两性离子化合物；类似反应条件下，得到4-羟基喹啉酮两性离子化合物．4-羟基香豆素类化合物与2，3-二氯-5，6-二氰基对苯醌反应获得了新的螺环化合物．
종술료불동조건하4-간기향두소류화합물여대곤적Michael가성반응급기반응궤리．재병동-수중，4-간기향두소류화합물여1，4-분곤반응생성2，3-이취대-1，4-분곤，여1，4-내곤반응생성2，3-이취대-1，4-채곤．재병동-수중，필정존재하，4-간기향두소류화합물여1，4-분곤반응생성량성리자화합물；유사반응조건하，득도4-간기규람동량성리자화합물．4-간기향두소류화합물여2，3-이록-5，6-이청기대분곤반응획득료신적라배화합물．
The Michael reactions of 4-hydroxycoumarins with p-quinones in different conditions and their reaction mechanism have been reviewed. 4-Hydroxycoumarins reacted with 1,4-benzoquinone in aqueous acetone to afford 2,3-disubstituted-1,4-benzoquinones, with 1,4-naphthoquinone to give corresponding derivatives. The zwitterions were synthesized when 4-hydroxycoumarins reacted with 1,4-benzoquinoe in the presence of pyridine in aqueous acetone. In the similar condition, the corresponding 4-hydroxyquinolinone zwitterions were generated. The new sipro-compounds were synthesized when 4-hydroxycoumarins reacted with 2,3-dichloro-5,6- dicyanobenzoquinone