文物保护与考古科学
文物保護與攷古科學
문물보호여고고과학
Sciences of Conservation and Archaeology
2010年
3期
15~20
,共null页
王永进 于群力 阎敏 马林燕 陈港泉
王永進 于群力 閻敏 馬林燕 陳港泉
왕영진 우군력 염민 마림연 진항천
离子色谱 壁画 可溶盐
離子色譜 壁畫 可溶鹽
리자색보 벽화 가용염
Ion chromatography; Murals ; Soluble salts
古代壁画的风化酥碱问题一直是壁画病害中最常见和最严重的问题之一,其主要原因是墙体中的可溶盐。了解壁画中可溶盐无机离子的特性及其活动规律可为解决古代壁画的酥碱问题提供科学参考和依据。为此,通过模拟壁画中可溶盐活动实验来揭示可溶性无机离子在壁画中的分布及活动规律。利用离子色谱仪检测分析壁画不同高度细泥层、粗泥层以及土坯层的可溶盐离子浓度。结果表明,试块细泥层中的Ca2+,Na+,和SO4 2+含量最高,说明这三种离子在壁画中的迁移能力最强,Cl-、NO3-、Mg2+的迁移能力居中,K+迁移能力最弱。离子迁移能力越强,在壁画表层富集程度就越高,各离子之间形成结晶盐的机率越大,对壁画破坏作用越大。本研究可为解决古代壁画盐害提供依据。
古代壁畫的風化酥堿問題一直是壁畫病害中最常見和最嚴重的問題之一,其主要原因是牆體中的可溶鹽。瞭解壁畫中可溶鹽無機離子的特性及其活動規律可為解決古代壁畫的酥堿問題提供科學參攷和依據。為此,通過模擬壁畫中可溶鹽活動實驗來揭示可溶性無機離子在壁畫中的分佈及活動規律。利用離子色譜儀檢測分析壁畫不同高度細泥層、粗泥層以及土坯層的可溶鹽離子濃度。結果錶明,試塊細泥層中的Ca2+,Na+,和SO4 2+含量最高,說明這三種離子在壁畫中的遷移能力最彊,Cl-、NO3-、Mg2+的遷移能力居中,K+遷移能力最弱。離子遷移能力越彊,在壁畫錶層富集程度就越高,各離子之間形成結晶鹽的機率越大,對壁畫破壞作用越大。本研究可為解決古代壁畫鹽害提供依據。
고대벽화적풍화소감문제일직시벽화병해중최상견화최엄중적문제지일,기주요원인시장체중적가용염。료해벽화중가용염무궤리자적특성급기활동규률가위해결고대벽화적소감문제제공과학삼고화의거。위차,통과모의벽화중가용염활동실험래게시가용성무궤리자재벽화중적분포급활동규률。이용리자색보의검측분석벽화불동고도세니층、조니층이급토배층적가용염리자농도。결과표명,시괴세니층중적Ca2+,Na+,화SO4 2+함량최고,설명저삼충리자재벽화중적천이능력최강,Cl-、NO3-、Mg2+적천이능력거중,K+천이능력최약。리자천이능력월강,재벽화표층부집정도취월고,각리자지간형성결정염적궤솔월대,대벽화파배작용월대。본연구가위해결고대벽화염해제공의거。
Efflorescence, caused mainly by the soluble salts in the wall, is one of the most common and serious diseases threatening ancient murals. Research on the characteristics and activities of inorganic ions in murals will provide a scientific reference basis for solving the problem of efflorescence in ancient murals. By simulating the mobility of soluble salts in murals, we tried to reveal the distribution and activities of inorganic ions. Detection and analysis of the concentration of soluble salts in fine mud layer, coarse mud layer and adobe layer at different height by ion chromatography showed that Ca2+ , Na + , and SO4 2- have the highest concentration in the fine mud layer of the test block, and therefore the highest mobility, followed by Cl- , NO3- , Mg2+ ;and K + which are weaker. The higher the mobility of the ion, the more it is enriched in the mural surface, and the higher the probability of its crystallization with other ions, and therefore the greater chance of damaging the mural. This study provides the basis for further research and the solution of salt damage of ancient murals.