CAJ | 학술논문

利用微聚焦能量色散X射线荧光光谱仪（EDXRF）、拉曼光谱仪（RS）、X射线电子能谱仪（XPS）等无损分析法，对重庆忠县翠屏山崖墓出土金银器的基体成分、表面腐蚀物成分以及其物相结构进行了系统的分析测试。结果表明：两个金器样品的含金量均高达90％，纯度较高。此外，还含有一定含量的银、铜、锌、镍、铷等杂质元素；银器中，大多数样品含银量高达97．38～98．85％，同时还含有少量硫、铬、镍、锌、金等杂质元素；银器表面附着的黑色的腐蚀物，经鉴定为Ag2S，红褐色腐蚀物的物相结构为Cu2O；值得关注的是，有一个银器样品含银95．2％，含铜3．19％，应为铜银合金，此结果对于探讨我国古代银铜合金技术发展与演变的研究，具有非常重要的意义。
이용미취초능량색산X사선형광광보의（EDXRF）、랍만광보의（RS）、X사선전자능보의（XPS）등무손분석법，대중경충현취병산애묘출토금은기적기체성분、표면부식물성분이급기물상결구진행료계통적분석측시。결과표명：량개금기양품적함금량균고체90％，순도교고。차외，환함유일정함량적은、동、자、얼、여등잡질원소；은기중，대다수양품함은량고체97．38～98．85％，동시환함유소량류、락、얼、자、금등잡질원소；은기표면부착적흑색적부식물，경감정위Ag2S，홍갈색부식물적물상결구위Cu2O；치득관주적시，유일개은기양품함은95．2％，함동3．19％，응위동은합금，차결과대우탐토아국고대은동합금기술발전여연변적연구，구유비상중요적의의。
By using nondestructive methods of Mirco-Energy dispersive X-ray Florence Probe, Raman Spectroscopy and X-ray electronic spectrometer, the gold and silver wares excavated from the Cliff Tombs in Cuiping Mountain Site, Zhong County of Chongqing, were analyzed. The analysis indicates that samples of the gold wares have high content of Au （〉90%）, with a certain amount of micro- elements such as Ag, Cu, Ni, Rb, etal, and that samples of silver have high content of Ag （97.38-98.85%）, with a certain amount of micro-elements S, Cr, Ni, Zn, Au, etal. The analysis also shows that black corrosion on the surface of silver is Ag2S, and that of brown is Cu2O. Meanwhile, content of Cu in one of silver samples is as high as 3.19%, with 95.3% of Ag, which is an important base for the research of ancient technique of Ag-Cu alloy.