CAJ | 학술논문

以2,2′-联吡啶-3,3′-二羧酸为配体合成了一个稀土-有机功能配合物[Tb2（C12H6O4N2）3（Phen）2（H2O）2·6H2O]n,并用X射线单晶衍射仪测定了其结构。检测了该配合物的荧光和磁性。结果表明：配合物在490.0、546.0、586.0和620.0nm处有四个特征荧光发射峰,它们分别归属于铽（Ⅲ）离子的5D4→7F6,5D4→7F5,5D4→7F4和5D4→7F3的电子跃迁;在低温下配合物有弱的反铁磁性。
이2,2′-련필정-3,3′-이최산위배체합성료일개희토-유궤공능배합물[Tb2（C12H6O4N2）3（Phen）2（H2O）2·6H2O]n,병용X사선단정연사의측정료기결구。검측료해배합물적형광화자성。결과표명：배합물재490.0、546.0、586.0화620.0nm처유사개특정형광발사봉,타문분별귀속우특（Ⅲ）리자적5D4→7F6,5D4→7F5,5D4→7F4화5D4→7F3적전자약천;재저온하배합물유약적반철자성。
A rare earth-organics complex [Tb2（C12H6O4N2）3（Phen）2（H2O）2·6H2O]n （1）with 2, 2′-hi- pyridine-3, 3′-dicarboxylic acid （H2L） as the ligand has been synthesized and characterized by single-crystal X-ray structure determination. The fluorescent and magnetic properties of complex 1 were investigated. The results show that 1 has four characteristic emission peaks arising from the transition of terbium （Ⅲ） ion as ^5D4→^7F6 （490. 0 nm）, ^5D4→^7F5 （546.0 nm）, ^5D4→^7F4 （586.0 nm） and ^5D4→^7F3 （620.0 nm）. The magnetic behavior shows that 1 exhibits weak antiferromagnetic property at low temperatures.