化工学报
化工學報
화공학보
CIESC Jorunal
2015年
9期
3726-3732
,共7页
杜若愚%刘伟%许滨滨%王小平%贺有周%郑旭煦
杜若愚%劉偉%許濱濱%王小平%賀有週%鄭旭煦
두약우%류위%허빈빈%왕소평%하유주%정욱후
重金属%污染%吸附%平衡%木质素%生物精炼
重金屬%汙染%吸附%平衡%木質素%生物精煉
중금속%오염%흡부%평형%목질소%생물정련
heavy metal%pollution%adsorption%equilibrium%lignin%biorefinery
采用有机酸法处理菜籽秆并从预处理废液中再生酸不溶性木质素固体,之后对模拟废液中的镉、铅离子进行吸附实验.探讨了木质素再生策略、结晶度、比表面积与基团组成对重金属离子吸附效果的影响.实验结果表明:该类再生木质素能有效地吸附模拟废液中的 Cd2+、Pb2+离子,其功能基团组成是影响吸附效果的关键因素.此外,两种木质素吸附剂吸附 Cd2+离子的能力均强于吸附 Pb2+离子的能力.
採用有機痠法處理菜籽稈併從預處理廢液中再生痠不溶性木質素固體,之後對模擬廢液中的鎘、鉛離子進行吸附實驗.探討瞭木質素再生策略、結晶度、比錶麵積與基糰組成對重金屬離子吸附效果的影響.實驗結果錶明:該類再生木質素能有效地吸附模擬廢液中的 Cd2+、Pb2+離子,其功能基糰組成是影響吸附效果的關鍵因素.此外,兩種木質素吸附劑吸附 Cd2+離子的能力均彊于吸附 Pb2+離子的能力.
채용유궤산법처리채자간병종예처리폐액중재생산불용성목질소고체,지후대모의폐액중적력、연리자진행흡부실험.탐토료목질소재생책략、결정도、비표면적여기단조성대중금속리자흡부효과적영향.실험결과표명:해류재생목질소능유효지흡부모의폐액중적 Cd2+、Pb2+리자,기공능기단조성시영향흡부효과적관건인소.차외,량충목질소흡부제흡부 Cd2+리자적능력균강우흡부 Pb2+리자적능력.
Acid-insoluble lignin solids were regenerated from the organic-acid pretreatment waste liquor of rapeseed stalk and were used for the adsorption of cadmium and lead ions from the artificial waste liquor. The influence of regeneration strategy, crystallinity, surface area and functional group content on the adsorption efficiency were studied in this paper. The results indicated that these two types regenerated lignins can effectively adsorb Cd2+, Pb2+ ions from artificial waste liquor and the content of functional group plays an key factor. In addition, the adsorbability of both two types of lignins is larger for Cd2+ ions than for Pb2+ ions.