功能材料
功能材料
공능재료
Journal of Functional Materials
2015年
16期
16106-16109,16114
,共5页
赵春宝%徐随春%朱宪忠%陈和祥%杨绪杰
趙春寶%徐隨春%硃憲忠%陳和祥%楊緒傑
조춘보%서수춘%주헌충%진화상%양서걸
氰酸酯树脂%石墨烯纳米片%氧化锌晶须%热性能%电绝缘性能
氰痠酯樹脂%石墨烯納米片%氧化鋅晶鬚%熱性能%電絕緣性能
청산지수지%석묵희납미편%양화자정수%열성능%전절연성능
cyanate ester resin%graphene nanoplatelets%zinc oxide whiskers%thermal properties%electrically insu-lating property
采用四针状氧化锌晶须(ZnOw)和石墨烯纳米片(GNP)改性氰酸酯树脂(CE)制备了系列导热绝缘复合材料,研究了填料的种类和用量对氰酸酯复合材料导热、绝缘及热稳定性能的影响。当树脂基体中加入50% ZnOw或10% GNP时,复合材料的热导率分别达到07.7和09.7W/(m·K),较纯树脂基体材料分别提高了185%和259%。将Z n O w与G N P混合填充氰酸酯树脂则更有利于提高复合材料的导热性能,当树脂基体中加入40% ZnOw 和10% GNP混合填料时,复合材料的热导率可达到15.4 W/(m·K),较纯树脂基体材料提高了470%,并且该复合材料仍能够保持良好的电绝缘性能。TGA结果表明,石墨烯纳米片和氧化锌晶须的加入可以明显提高氰酸酯树脂复合材料的热稳定性。
採用四針狀氧化鋅晶鬚(ZnOw)和石墨烯納米片(GNP)改性氰痠酯樹脂(CE)製備瞭繫列導熱絕緣複閤材料,研究瞭填料的種類和用量對氰痠酯複閤材料導熱、絕緣及熱穩定性能的影響。噹樹脂基體中加入50% ZnOw或10% GNP時,複閤材料的熱導率分彆達到07.7和09.7W/(m·K),較純樹脂基體材料分彆提高瞭185%和259%。將Z n O w與G N P混閤填充氰痠酯樹脂則更有利于提高複閤材料的導熱性能,噹樹脂基體中加入40% ZnOw 和10% GNP混閤填料時,複閤材料的熱導率可達到15.4 W/(m·K),較純樹脂基體材料提高瞭470%,併且該複閤材料仍能夠保持良好的電絕緣性能。TGA結果錶明,石墨烯納米片和氧化鋅晶鬚的加入可以明顯提高氰痠酯樹脂複閤材料的熱穩定性。
채용사침상양화자정수(ZnOw)화석묵희납미편(GNP)개성청산지수지(CE)제비료계렬도열절연복합재료,연구료전료적충류화용량대청산지복합재료도열、절연급열은정성능적영향。당수지기체중가입50% ZnOw혹10% GNP시,복합재료적열도솔분별체도07.7화09.7W/(m·K),교순수지기체재료분별제고료185%화259%。장Z n O w여G N P혼합전충청산지수지칙경유리우제고복합재료적도열성능,당수지기체중가입40% ZnOw 화10% GNP혼합전료시,복합재료적열도솔가체도15.4 W/(m·K),교순수지기체재료제고료470%,병차해복합재료잉능구보지량호적전절연성능。TGA결과표명,석묵희납미편화양화자정수적가입가이명현제고청산지수지복합재료적열은정성。
A series of thermally conductive cyanate ester resin (CE) composites filled with tetrapod‐shaped zinc oxide whiskers (ZnOw) and graphene nanoplatelets (GNP) were prepared .Effects of the varieties and amounts of the fillers on thermal conductivity ,electrical insulation and thermal stability properties of the composites were investigated .By adding 50% ZnOw or 10% GNP to cyanate ester resin ,the thermal conductivity of the composites reached 0 7.7 and 0 .97 W/(m · K) ,which were respectively 185% and 259% higher than that of pure CE matrix .Incorporating the mixture of ZnOw and GNP into cyanate ester resin could facilitate to improve the thermal conductivity of the composites .The thermal conductivity of the CE composite is as high as 1 5.4 W/(m · K) with 40% ZnOw and 10% GNP ,which is 470% higher than that of pure CE matrix ,while its better e‐lectrical insulation is maintained .TGA results showed that the addition of graphene nanoplatelets and zinc oxide whiskers can improve the thermal stability of CE composites significantly .