功能材料
功能材料
공능재료
Journal of Functional Materials
2015年
17期
17107-17110
,共4页
吕娇%梁兵%王刚%何冬青%唐禹
呂嬌%樑兵%王剛%何鼕青%唐禹
려교%량병%왕강%하동청%당우
阻燃剂%含磷%无卤%合成
阻燃劑%含燐%無滷%閤成
조연제%함린%무서%합성
flame retardant%phosphorus-containing%halogen free%synthesis
以苯膦酰二氯(PPD)和对苯二酚(HQ)为原料,合成了含磷阻燃剂2‐(4‐羟苯基)苯膦氧化物(B H‐PPO),并通过FT‐IR、1 H NMR、13C NMR、ESI‐MS对该化合物结构进行了表征。合成BHPPO的最佳工艺条件是在氮气保护条件下,n(PPD)∶ n(HQ)=1∶24.,反应物浓度为08. mol/L ,反应温度为130℃,反应时间为10 h ,其收率为917.3%;并通过热重分析研究了BHPPO的热稳定性能。
以苯膦酰二氯(PPD)和對苯二酚(HQ)為原料,閤成瞭含燐阻燃劑2‐(4‐羥苯基)苯膦氧化物(B H‐PPO),併通過FT‐IR、1 H NMR、13C NMR、ESI‐MS對該化閤物結構進行瞭錶徵。閤成BHPPO的最佳工藝條件是在氮氣保護條件下,n(PPD)∶ n(HQ)=1∶24.,反應物濃度為08. mol/L ,反應溫度為130℃,反應時間為10 h ,其收率為917.3%;併通過熱重分析研究瞭BHPPO的熱穩定性能。
이분련선이록(PPD)화대분이분(HQ)위원료,합성료함린조연제2‐(4‐간분기)분련양화물(B H‐PPO),병통과FT‐IR、1 H NMR、13C NMR、ESI‐MS대해화합물결구진행료표정。합성BHPPO적최가공예조건시재담기보호조건하,n(PPD)∶ n(HQ)=1∶24.,반응물농도위08. mol/L ,반응온도위130℃,반응시간위10 h ,기수솔위917.3%;병통과열중분석연구료BHPPO적열은정성능。
A phosphorus‐containing flame retardant bis (4‐hydroxyphenyl) phenyl phosphine oxide (BHPPO ) was synthesized by the reaction of phenyl phosphonic dichloride(PPD) and hydroquinone(HQ) .The chemical structure of the obtained compound was identified by FT‐IR ,1 H NMR ,13C NMR and ESI‐MS .The optimum reaction conditions were determined as follows :in nitrogen atmosphere ,the mole ratio of phenyl phosphonic di‐chloride and hydroquinone was 1∶2 4. ,40 mL xylene as solvent ,reaction temperature was 130 ℃ ,the reaction time was 10 h ,yield was 91 7.3% .And the thermal stability of BHPPO was tested by MP and TG .