CAJ | 학술논문

以2，4‐二氯苯氧乙酸（HD）为配体，合成了新的铽、镝的二元、三元配合物。测定了配合物的元素组成，并对其进行热重分析，表明配合物的通式为RED3 H2 O 、RED3 phen（RE＝ Tb 、Dy ；D＝2，4‐二氯苯氧乙酸根；phen＝邻菲罗啉）；对配合物进行了红外光谱、紫外光谱、荧光光谱、热重分析。结果表明，二元配合物在140℃左右失去结晶水，三元配合物具有较好的稳定性；配合物T bD3 H2 O、T bD3 phen具有荧光性能，配合物DyD3 H2 O、DyD3 phen不发光；并进一步讨论了掺杂Y3＋离子、Eu3＋离子对三元配合物T bD3 phen荧光强度的影响。
이2，4‐이록분양을산（HD）위배체，합성료신적특、적적이원、삼원배합물。측정료배합물적원소조성，병대기진행열중분석，표명배합물적통식위RED3 H2 O 、RED3 phen（RE＝ Tb 、Dy ；D＝2，4‐이록분양을산근；phen＝린비라람）；대배합물진행료홍외광보、자외광보、형광광보、열중분석。결과표명，이원배합물재140℃좌우실거결정수，삼원배합물구유교호적은정성；배합물T bD3 H2 O、T bD3 phen구유형광성능，배합물DyD3 H2 O、DyD3 phen불발광；병진일보토론료참잡Y3＋리자、Eu3＋리자대삼원배합물T bD3 phen형광강도적영향。
The binary and ternary complexes of Terbium ,Dysprosium were synthesized with 2 ,4‐dichlorophenoxyacetic acid as the first ligand ,1 ,10‐phenanthroline as the second ligand ,By ele‐mental analysis ,EDTA complexometric titration and TG‐DTG to determine the molecular formula is :RED3 H2 O 、RED3 phen (RE = Tb ,Dy ;D = 2 ,4‐ Dichlorophenoxyacetic acid ion ;phen = 1 ,10‐phenanthroline ) ;Its structure was characterized by IR ,UV ;and the fluorescence spectra and the TG‐DTG curves of the complexes were measured .The results indicated that the crystal water of RED3 H2 O was lost at about140℃ ,and RED3 phen had better thermal stability ;The binary and ternary complexes of Terbium had the property of luminescence;The influence of Y3+ ,Eu3+ on luminescence intensity to TbD3 phen was further researched .