功能材料
功能材料
공능재료
Journal of Functional Materials
2015年
18期
18112-18116
,共5页
贮氢合金%低温性能%热处理%甩片%退火处理
貯氫閤金%低溫性能%熱處理%甩片%退火處理
저경합금%저온성능%열처리%솔편%퇴화처리
hydrogen storage alloys%low temperature%preparation process%rapid quenching%annealed
对铸态 RE(NiCoMnAl)5合金1173 K 退火、甩片、甩片+1173 K 退火的工艺进行处理。合金通过XRD、SEM等分析发现,通过1173 K 退火及甩片+1173 K退火后其成分变得更加均匀。电化学和动力学测试结果表明,铸态合金1173 K 退火及甩片+1173 K退火具有良好的常温电化学性能,而铸态及甩片+1173 K退火具有良好的低温放电性能,甩片+1173 K退火处理合金具有最佳的综合电化学性能。
對鑄態 RE(NiCoMnAl)5閤金1173 K 退火、甩片、甩片+1173 K 退火的工藝進行處理。閤金通過XRD、SEM等分析髮現,通過1173 K 退火及甩片+1173 K退火後其成分變得更加均勻。電化學和動力學測試結果錶明,鑄態閤金1173 K 退火及甩片+1173 K退火具有良好的常溫電化學性能,而鑄態及甩片+1173 K退火具有良好的低溫放電性能,甩片+1173 K退火處理閤金具有最佳的綜閤電化學性能。
대주태 RE(NiCoMnAl)5합금1173 K 퇴화、솔편、솔편+1173 K 퇴화적공예진행처리。합금통과XRD、SEM등분석발현,통과1173 K 퇴화급솔편+1173 K퇴화후기성분변득경가균균。전화학화동역학측시결과표명,주태합금1173 K 퇴화급솔편+1173 K퇴화구유량호적상온전화학성능,이주태급솔편+1173 K퇴화구유량호적저온방전성능,솔편+1173 K퇴화처리합금구유최가적종합전화학성능。
The effects of rapid quenching,1 1 7 3 K annealed and rapid quenching with 1 1 7 3 K annealed on the electrochemical performances of as-cast RE(NiCoMnAl)5 hydrogen storage alloys were comparatively investiga-ted to explore the optimal process.XRD,SEM analysis found that the composition become more homogenous after 1 173 K annealed.The results of electrochemical and kinetic measurement show that,the as-cast alloy of 1 173 K annealed and rapid quenching with 1 173 K annealed had the good electrochemical performance at room temperature,while the as-cast and rapid quenching with 1 173 K annealed had the good electrochemical per-formance at low temperature.It indicates the rapid quenching with 1 173 K annealed alloy had the best overall electrochemical properties.