应用化工
應用化工
응용화공
Applied Chemical Industry
2015年
9期
1631-1634,1638
,共5页
李静萍%仝云霄%管振杰%杨佳静%张念%刘洋
李靜萍%仝雲霄%管振傑%楊佳靜%張唸%劉洋
리정평%동운소%관진걸%양가정%장념%류양
腐植酸%负载Ti/Fe%As(Ⅲ)%吸附
腐植痠%負載Ti/Fe%As(Ⅲ)%吸附
부식산%부재Ti/Fe%As(Ⅲ)%흡부
humic acid%loaded Ti/Fe%As(Ⅲ)%adsorption
制备了负载Ti/Fe腐植酸吸附剂,采用SEM、XRD等分析方法对负载Ti/Fe腐植酸的结构进行了表征,并对As(Ⅲ)进行了吸附性能的研究。结果表明,负载Ti/Fe腐植酸吸附剂较负载前的腐植酸,表面负载了大量类球状颗粒,内部孔道面积和表面积增加,活性吸附位点的数量增大,吸附能力有了明显的提高。在55℃、pH值为6、吸附平衡时间为120 min时,负载Ti/Fe腐植酸吸附剂对As (Ⅲ)有较好的吸附效果。负载Ti/Fe腐植酸吸附剂对As(Ⅲ)的吸附符合Freundlich吸附模型。
製備瞭負載Ti/Fe腐植痠吸附劑,採用SEM、XRD等分析方法對負載Ti/Fe腐植痠的結構進行瞭錶徵,併對As(Ⅲ)進行瞭吸附性能的研究。結果錶明,負載Ti/Fe腐植痠吸附劑較負載前的腐植痠,錶麵負載瞭大量類毬狀顆粒,內部孔道麵積和錶麵積增加,活性吸附位點的數量增大,吸附能力有瞭明顯的提高。在55℃、pH值為6、吸附平衡時間為120 min時,負載Ti/Fe腐植痠吸附劑對As (Ⅲ)有較好的吸附效果。負載Ti/Fe腐植痠吸附劑對As(Ⅲ)的吸附符閤Freundlich吸附模型。
제비료부재Ti/Fe부식산흡부제,채용SEM、XRD등분석방법대부재Ti/Fe부식산적결구진행료표정,병대As(Ⅲ)진행료흡부성능적연구。결과표명,부재Ti/Fe부식산흡부제교부재전적부식산,표면부재료대량류구상과립,내부공도면적화표면적증가,활성흡부위점적수량증대,흡부능력유료명현적제고。재55℃、pH치위6、흡부평형시간위120 min시,부재Ti/Fe부식산흡부제대As (Ⅲ)유교호적흡부효과。부재Ti/Fe부식산흡부제대As(Ⅲ)적흡부부합Freundlich흡부모형。
The humic acid adsorbent loaded Ti/Fe was prepared. The structure of the adsorbent was char-acterized by SEM,XRD etc. ,and the adsorption performance for As(Ⅲ) was studied. The result showed that a large number of spherical particles were loaded on the surface of the adsorbent,the internal pore size and surface area were increased and the quantity of active adsorption sites was improved. So the ad-sorption capacity of the adsorbent was promoted compared with the humic acid before loading. The humic acid adsorbent loaded Ti/Fe better adsorption effect for As (Ⅲ) when pH value was 6 and adsorption equilibrium time was 120 min at 55 ℃. The adsorption performance for As(Ⅲ) of the humic acid adsor-bent loaded Ti/Fe for As(Ⅲ) accorded with the Freundlich equation.