化工进展
化工進展
화공진전
Chemical Industry and Engineering Progress
2015年
9期
3363-3369
,共7页
冯颖%王潇潇%童义平%文思
馮穎%王瀟瀟%童義平%文思
풍영%왕소소%동의평%문사
钨/钼酸盐%纳米材料%白光发光二极管%制备%优化
鎢/鉬痠鹽%納米材料%白光髮光二極管%製備%優化
오/목산염%납미재료%백광발광이겁관%제비%우화
tungstate and molybdate%nanomaterials%white light-emitting%preparation%optimization
红色荧光粉是白光发光二极管(LED)照明应用中的一种关键发光材料,有效改善红色荧光粉的发光性能对制造出高显色指数、低色温、大功率白光LED起到重要作用.荧光粉的合成工艺是影响红粉的表面形貌和光学性能的因素之一.本文以钨/钼酸盐基红色荧光粉为依托,对近年来红粉合成工艺的应用和研究进行了简要分析,详细介绍了国内外制备钨/钼酸盐红色荧光粉的合成方法,如高温固相法、溶胶-凝胶法、沉淀法、水热法、喷雾热解法、燃烧法等的研究现状,讨论了不同制备方法的生产流程、工艺特点以及相关制备技术参数对合成荧光粉性能的影响,并对其未来在计算机模拟、现代技术辅助以及机理研究等方面的发展方向进行了展望.
紅色熒光粉是白光髮光二極管(LED)照明應用中的一種關鍵髮光材料,有效改善紅色熒光粉的髮光性能對製造齣高顯色指數、低色溫、大功率白光LED起到重要作用.熒光粉的閤成工藝是影響紅粉的錶麵形貌和光學性能的因素之一.本文以鎢/鉬痠鹽基紅色熒光粉為依託,對近年來紅粉閤成工藝的應用和研究進行瞭簡要分析,詳細介紹瞭國內外製備鎢/鉬痠鹽紅色熒光粉的閤成方法,如高溫固相法、溶膠-凝膠法、沉澱法、水熱法、噴霧熱解法、燃燒法等的研究現狀,討論瞭不同製備方法的生產流程、工藝特點以及相關製備技術參數對閤成熒光粉性能的影響,併對其未來在計算機模擬、現代技術輔助以及機理研究等方麵的髮展方嚮進行瞭展望.
홍색형광분시백광발광이겁관(LED)조명응용중적일충관건발광재료,유효개선홍색형광분적발광성능대제조출고현색지수、저색온、대공솔백광LED기도중요작용.형광분적합성공예시영향홍분적표면형모화광학성능적인소지일.본문이오/목산염기홍색형광분위의탁,대근년래홍분합성공예적응용화연구진행료간요분석,상세개소료국내외제비오/목산염홍색형광분적합성방법,여고온고상법、용효-응효법、침정법、수열법、분무열해법、연소법등적연구현상,토론료불동제비방법적생산류정、공예특점이급상관제비기술삼수대합성형광분성능적영향,병대기미래재계산궤모의、현대기술보조이급궤리연구등방면적발전방향진행료전망.
Red-emitting phosphor is a crucial luminescent material in white LED lighting applications. It is important to effectively improve the properties of red phosphor for preparing high color rendering index,low temperature,and high power white LED. Synthetic method of phosphor is one of the factors to influence the surface morphology and optical properties of red phosphor. In this paper,based on the tungstate and molybdate red phosphor system,the application and research on synthesis technique in recent years were analyzed. The present research situation for the synthesis method of tungstate and molybdate red phosphor system was introduced in detail,such as high temperature solid phase method, sol-gel method,precipitation method,hydrothermal method,spray pyrolysis,and combustion method. The processes and characteristics of different preparation methods and the influence on the performance of phosphor were discussed,and the future development direction,such as computer simulation,modern technology assistant,mechanism and so on,was prospected.