CAJ | 학술논문

双功能催化剂的研究一直是纤维素降解制备高值化学品过程中催化剂研究的热点问题,但其在催化纤维素降解过程中还存在着催化机理不明确、目标产物选择性不高、水热稳定性不好等问题.本文简述了目前最受关注的含Ru、Ni、W、Pt等体系的双功能催化剂和不同载体影响下的双功能催化剂在纤维素制备C6多元醇、低碳多元醇(C2~C3)等化学品中的研究进展,初步总结了单金属、双金属体系和不同载体的双功能催化剂研究的前沿进展,分析表明不同活性金属之间配比以及活性金属与载体之间的相互作用均对催化效果产生重大影响;最后对其在纤维素制备多元醇中的应用前景进行了展望,指出继续研究活性金属之间及其与载体之间的相互作用将是今后研究的重点方向.
쌍공능최화제적연구일직시섬유소강해제비고치화학품과정중최화제연구적열점문제,단기재최화섬유소강해과정중환존재착최화궤리불명학、목표산물선택성불고、수열은정성불호등문제.본문간술료목전최수관주적함Ru、Ni、W、Pt등체계적쌍공능최화제화불동재체영향하적쌍공능최화제재섬유소제비C6다원순、저탄다원순(C2~C3)등화학품중적연구진전,초보총결료단금속、쌍금속체계화불동재체적쌍공능최화제연구적전연진전,분석표명불동활성금속지간배비이급활성금속여재체지간적상호작용균대최화효과산생중대영향;최후대기재섬유소제비다원순중적응용전경진행료전망,지출계속연구활성금속지간급기여재체지간적상호작용장시금후연구적중점방향.
The research on heterogeneous bifunctional catalysts (BFC) is the hot theme in cellulose processing to obtain green chemicals. But in this process,the BFC still had some fatal problems needed to be solved,such as the mechanism of the catalytic process,and its low selectivity for aimed products and hydrothermal stability. The research progress in most concerned BFC containing active metal components,such as Ru,Ni,W,and Pt,and the interacts between metal components and carriers for the application in cellulose to hexabasic alcohols and low carbon polyols (C2-C3),were introduced, and the recent advances in mono-metallic,bi-metallic BFC and the BFC based on different carriers were simply summarized. The analysis results demonstrated the ratios of different metal components and the internal interacts between active metals and carriers had a great influence on catalytic results. The future study should be focused on the mechanism of interacts of catalytic constituents and carriers.