贵金属
貴金屬
귀금속
Precious Metals
2015年
3期
55-59,66
,共6页
李桂华%张凤霞%刘化峰%黄准%祝培明
李桂華%張鳳霞%劉化峰%黃準%祝培明
리계화%장봉하%류화봉%황준%축배명
分析化学%含金基体%F检验法%t检验法%均匀性
分析化學%含金基體%F檢驗法%t檢驗法%均勻性
분석화학%함금기체%F검험법%t검험법%균균성
analytical chemistry%gold matrix%F test%t test%homogeneity
为了消除黄金基体对部分被测(杂质)元素产生的干扰与抑制作用,采用基体匹配法,配制了含金基体混合多元素标准溶液.用ICP-AES法对该含金基体溶液中的Ag、Cu、Fe、Zn元素进行了均匀性检验.采用F和t检验法联用统计处理数据对该溶液进行了均匀性评价.检验结果表明瓶间和瓶内的均值和方差不存在显著性差异,证明该含金基体混合多元素标准溶液是均匀的.
為瞭消除黃金基體對部分被測(雜質)元素產生的榦擾與抑製作用,採用基體匹配法,配製瞭含金基體混閤多元素標準溶液.用ICP-AES法對該含金基體溶液中的Ag、Cu、Fe、Zn元素進行瞭均勻性檢驗.採用F和t檢驗法聯用統計處理數據對該溶液進行瞭均勻性評價.檢驗結果錶明瓶間和瓶內的均值和方差不存在顯著性差異,證明該含金基體混閤多元素標準溶液是均勻的.
위료소제황금기체대부분피측(잡질)원소산생적간우여억제작용,채용기체필배법,배제료함금기체혼합다원소표준용액.용ICP-AES법대해함금기체용액중적Ag、Cu、Fe、Zn원소진행료균균성검험.채용F화t검험법련용통계처리수거대해용액진행료균균성평개.검험결과표명병간화병내적균치화방차불존재현저성차이,증명해함금기체혼합다원소표준용액시균균적.
In order to eliminate the interference and inhibition effects of gold matrix on impurity elements, the gold matrix multi-element mixed standard solution was prepared using the matrix matching method. The homogeneity tests on Ag, Cu, Fe and Zn elements in the gold matrix multi-element mixed standard solution were performed by ICP-AES. And the homogeneity of the standard solution was evaluated by adopting the statistical data processing methods:F test andt test. The results showed that there were no significant differences in mean and variance, indicating that the gold matrix multi-element mixed standard solution was homogeneous.