CAJ | 학술논문

先以甘油和碳酸二甲酯为原料合成碳酸甘油酯(GC)，再以 GC 为溶剂制备浓度为0.75 mol/L 的高氯酸锂电解质溶液，测得该电解液的电导率为3.34 mS/cm；以该电解液为增塑剂，聚丙烯腈-甲基丙烯酸甲酯(P (AN-MMA))为高分子骨架制备凝胶电解质，当V (增塑剂)∶V (聚合物)=0.75时，凝胶电解质室温下的电导率为0.94 mS/cm.将其用于结构为玻璃/FTO/WO 3/电解质/CeO 2-TiO 2/FTO/玻璃的电致变色器件，该器件在550 nm 处的变色范围为20%，变色效率为6.89 cm2/C.
선이감유화탄산이갑지위원료합성탄산감유지(GC)，재이 GC 위용제제비농도위0.75 mol/L 적고록산리전해질용액，측득해전해액적전도솔위3.34 mS/cm；이해전해액위증소제，취병희정-갑기병희산갑지(P (AN-MMA))위고분자골가제비응효전해질，당V (증소제)∶V (취합물)=0.75시，응효전해질실온하적전도솔위0.94 mS/cm.장기용우결구위파리/FTO/WO 3/전해질/CeO 2-TiO 2/FTO/파리적전치변색기건，해기건재550 nm 처적변색범위위20%，변색효솔위6.89 cm2/C.
Glycerol carbonate was synthesized by the transesterification of glycerol with dimethyl carbonate in the presence of calcium oxide as catalyst.The liquid electrolyte was composed of lithium perchlorate (LiClO 4 )as solute and glycerol carbonate as solvent.The ionic conductivity of the electrolyte with 0.75 mol/L LiClO 4 in GC was 3.34 mS/cm.As a plasticizer,the electrolyte was used to prepare poly (acrylonitrile-methyl methacrylate)(P (AN-MMA))based gel electrolyte.The gel electrolyte was obtained by putting the P(AN-MMA)membrane in the liquid electrolyte.The gelled membrane sucked with 75% of the liquid electrolyte vs the dried membrane presented an ionic conductivity of 0.94 mS/cm at room temperature. When the gel electrolyte applied to the electrochromic devices (ECD)with the configuration glass/FTO/WO 3/electrolyte/CeO 2-TiO 2/FTO/glass,the transmittance change of the ECD reached 20% at 550 nm and the coloration efficiency of the ECD was 6.89 cm2/C.